File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1002/anie.200219832
- Scopus: eid_2-s2.0-0037432907
- PMID: 12698461
- WOS: WOS:000182496200012
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Observation of intramolecular C-H⋯F-C contacts in non-metallocene polyolefin catalysts: Model for weak attractive interactions between polymer chain and noninnocent ligand
Title | Observation of intramolecular C-H⋯F-C contacts in non-metallocene polyolefin catalysts: Model for weak attractive interactions between polymer chain and noninnocent ligand |
---|---|
Authors | |
Keywords | Fluorine Hydrogen bonds Polymerization Through-space interactions Zirconium |
Issue Date | 2003 |
Publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home |
Citation | Angewandte Chemie - International Edition, 2003, v. 42 n. 14, p. 1628-1632 How to Cite? |
Abstract | Attracting attention! The existence of attractive interactions between a functionalized ancillary ligand and a growing alkyl chain is a highly novel concept in olefin polymerization reactions (see scheme). Such interactions must be very weak so that the chain-propagation process is not perturbed, and "controversial" hydrogen bonds with strong dispersive character, such as CH⋯FC, are therefore ideal in this role (see scheme). |
Persistent Identifier | http://hdl.handle.net/10722/167780 |
ISSN | 2023 Impact Factor: 16.1 2023 SCImago Journal Rankings: 5.300 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kui, SCF | en_HK |
dc.contributor.author | Zhu, N | en_HK |
dc.contributor.author | Chan, MCW | en_HK |
dc.date.accessioned | 2012-10-08T03:11:28Z | - |
dc.date.available | 2012-10-08T03:11:28Z | - |
dc.date.issued | 2003 | en_HK |
dc.identifier.citation | Angewandte Chemie - International Edition, 2003, v. 42 n. 14, p. 1628-1632 | en_HK |
dc.identifier.issn | 1433-7851 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/167780 | - |
dc.description.abstract | Attracting attention! The existence of attractive interactions between a functionalized ancillary ligand and a growing alkyl chain is a highly novel concept in olefin polymerization reactions (see scheme). Such interactions must be very weak so that the chain-propagation process is not perturbed, and "controversial" hydrogen bonds with strong dispersive character, such as CH⋯FC, are therefore ideal in this role (see scheme). | en_HK |
dc.language | eng | en_US |
dc.publisher | Wiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home | en_HK |
dc.relation.ispartof | Angewandte Chemie - International Edition | en_HK |
dc.subject | Fluorine | en_HK |
dc.subject | Hydrogen bonds | en_HK |
dc.subject | Polymerization | en_HK |
dc.subject | Through-space interactions | en_HK |
dc.subject | Zirconium | en_HK |
dc.title | Observation of intramolecular C-H⋯F-C contacts in non-metallocene polyolefin catalysts: Model for weak attractive interactions between polymer chain and noninnocent ligand | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Kui, SCF: stevenku@hku.hk | en_HK |
dc.identifier.email | Zhu, N: nzhu@hkucc.hku.hk | en_HK |
dc.identifier.authority | Kui, SCF=rp00715 | en_HK |
dc.identifier.authority | Zhu, N=rp00845 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1002/anie.200219832 | en_HK |
dc.identifier.pmid | 12698461 | - |
dc.identifier.scopus | eid_2-s2.0-0037432907 | en_HK |
dc.identifier.hkuros | 93656 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0037432907&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 42 | en_HK |
dc.identifier.issue | 14 | en_HK |
dc.identifier.spage | 1628 | en_HK |
dc.identifier.epage | 1632 | en_HK |
dc.identifier.isi | WOS:000182496200012 | - |
dc.publisher.place | Germany | en_HK |
dc.identifier.scopusauthorid | Kui, SCF=6506763660 | en_HK |
dc.identifier.scopusauthorid | Zhu, N=7201449530 | en_HK |
dc.identifier.scopusauthorid | Chan, MCW=7402598116 | en_HK |
dc.identifier.issnl | 1433-7851 | - |