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Article: Solvent-induced aggregation through metal···metal/π···π interactions: Large solvatochrmism of luminescent organoplatinum(II) terpyridyl complexes

TitleSolvent-induced aggregation through metal···metal/π···π interactions: Large solvatochrmism of luminescent organoplatinum(II) terpyridyl complexes
Authors
Yam, VWWWong, KMCZhu, N
Issue Date2002
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal Of The American Chemical Society, 2002, v. 124 n. 23, p. 6506-6507 How to Cite?
DOI: http://dx.doi.org/10.1021/ja025811c
AbstractA dramatic color change and tremendous emission enhancement have been "switched on" upon increasing diethyl ether ratio in acetonitrile or acetone solution of [Pt(tpy)(C≡C-C≡CH)]OTf, attributed to the formation of Pt⋯Pt and π-π interactions. Two crystal forms (dark-green and red) of [Pt(tpy)(C≡C-C≡CH)]OTf, together with [Pt(tBu3-tpy)(C≡C-C≡CH)]OTf, show different crystal-packing modes as revealed by X-ray crystallography. Copyright © 2002 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/167753
ISSN
0002-7863
2023 Impact Factor: 14.4
2023 SCImago Journal Rankings: 5.489
ISI Accession Number ID
WOS:000176059100001
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorWong, KMCen_HK
dc.contributor.authorZhu, Nen_HK
dc.date.accessioned2012-10-08T03:11:02Z-
dc.date.available2012-10-08T03:11:02Z-
dc.date.issued2002en_HK
dc.identifier.citationJournal Of The American Chemical Society, 2002, v. 124 n. 23, p. 6506-6507en_HK
dc.identifier.issn0002-7863en_HK
dc.identifier.urihttp://hdl.handle.net/10722/167753-
dc.description.abstractA dramatic color change and tremendous emission enhancement have been "switched on" upon increasing diethyl ether ratio in acetonitrile or acetone solution of [Pt(tpy)(C≡C-C≡CH)]OTf, attributed to the formation of Pt⋯Pt and π-π interactions. Two crystal forms (dark-green and red) of [Pt(tpy)(C≡C-C≡CH)]OTf, together with [Pt(tBu3-tpy)(C≡C-C≡CH)]OTf, show different crystal-packing modes as revealed by X-ray crystallography. Copyright © 2002 American Chemical Society.en_HK
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.htmlen_HK
dc.relation.ispartofJournal of the American Chemical Societyen_HK
dc.titleSolvent-induced aggregation through metal···metal/π···π interactions: Large solvatochrmism of luminescent organoplatinum(II) terpyridyl complexesen_HK
dc.typeArticleen_HK
dc.identifier.emailYam, VWW: wwyam@hku.hken_HK
dc.identifier.emailWong, KMC: wongmc@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.identifier.authorityWong, KMC=rp00809en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ja025811cen_HK
dc.identifier.pmid12047150-
dc.identifier.scopuseid_2-s2.0-0037067013en_HK
dc.identifier.hkuros69094-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037067013&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume124en_HK
dc.identifier.issue23en_HK
dc.identifier.spage6506en_HK
dc.identifier.epage6507en_HK
dc.identifier.isiWOS:000176059100001-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridWong, KMC=8061067200en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.issnl0002-7863-

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