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Article: Synthesis and structural characterization of a novel luminescent tetranuclear mixed-metal platimim(II)- Copper (I) complex
Title | Synthesis and structural characterization of a novel luminescent tetranuclear mixed-metal platimim(II)- Copper (I) complex |
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Authors | |
Issue Date | 2001 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics |
Citation | Organometallics, 2001, v. 20 n. 4, p. 721-726 How to Cite? |
Abstract | A novel tetranuclear mixed-metal platinum(II)-copper(I) complex, [Pt 2(dppm) 2(C≡CPh) 4· {Cu(MeCN)} 2](PF 6) 2, has been synthesized by the reaction of its precursor complex, [Pt 2(dppm) 2(C=CPh) 4], with [Cu(MeCN) 4]PF 6. Their crystal structures and luminescence behavior have been determined. Perturbation of the spectroscopic and emission properties has been accomplished by a change in the Pt⋯Pt distance as well as the π-acceptor ability of the alkynyl unit via Cu(I) coordination. © 2001 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/167685 |
ISSN | 2023 Impact Factor: 2.5 2023 SCImago Journal Rankings: 0.654 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yam, VWW | en_US |
dc.contributor.author | Yu, KL | en_US |
dc.contributor.author | Wong, KMC | en_US |
dc.contributor.author | Cheung, KK | en_US |
dc.date.accessioned | 2012-10-08T03:10:00Z | - |
dc.date.available | 2012-10-08T03:10:00Z | - |
dc.date.issued | 2001 | en_US |
dc.identifier.citation | Organometallics, 2001, v. 20 n. 4, p. 721-726 | en_US |
dc.identifier.issn | 0276-7333 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167685 | - |
dc.description.abstract | A novel tetranuclear mixed-metal platinum(II)-copper(I) complex, [Pt 2(dppm) 2(C≡CPh) 4· {Cu(MeCN)} 2](PF 6) 2, has been synthesized by the reaction of its precursor complex, [Pt 2(dppm) 2(C=CPh) 4], with [Cu(MeCN) 4]PF 6. Their crystal structures and luminescence behavior have been determined. Perturbation of the spectroscopic and emission properties has been accomplished by a change in the Pt⋯Pt distance as well as the π-acceptor ability of the alkynyl unit via Cu(I) coordination. © 2001 American Chemical Society. | en_US |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics | en_US |
dc.relation.ispartof | Organometallics | en_US |
dc.title | Synthesis and structural characterization of a novel luminescent tetranuclear mixed-metal platimim(II)- Copper (I) complex | en_US |
dc.type | Article | en_US |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_US |
dc.identifier.email | Wong, KMC:wongmc@hku.hk | en_US |
dc.identifier.authority | Yam, VWW=rp00822 | en_US |
dc.identifier.authority | Wong, KMC=rp00809 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/om000713q | - |
dc.identifier.scopus | eid_2-s2.0-0035250429 | en_US |
dc.identifier.hkuros | 62526 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0035250429&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 20 | en_US |
dc.identifier.issue | 4 | en_US |
dc.identifier.spage | 721 | en_US |
dc.identifier.epage | 726 | en_US |
dc.identifier.isi | WOS:000167135000020 | - |
dc.publisher.place | United States | en_US |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_US |
dc.identifier.scopusauthorid | Yu, KL=7403385872 | en_US |
dc.identifier.scopusauthorid | Wong, KMC=8061067200 | en_US |
dc.identifier.scopusauthorid | Cheung, KK=7402406613 | en_US |
dc.identifier.issnl | 0276-7333 | - |