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Article: Synthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands

TitleSynthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands
Authors
Yam, VWWChu, BWKKo, CCCheung, KK
Issue Date2001
Citation
Journal Of The Chemical Society, Dalton Transactions, 2001 n. 12, p. 1911-1919 How to Cite?
DOI: http://dx.doi.org/10.1039/B100696G
AbstractA series of ruthenium(II) orthometallated aminocarbene complexes have been synthesized and characterized. Their electrochemistry, electronic absorption, emission, and the crystal structures of [Ru(phen) 2{=C(CH 2Ph)NHC 6H 4}]CF 3SO 3, [Ru(bpy) 2{=C(CH 2Ph)NMeC 6H 4}]PF 6 and [Ru(bpy) 2{=C(CH 2C 4H 3S)NHC 6H 4}]CF 3SO 3 have been studied. The nature of the electronic transitions and the origin of the emission are discussed and an assignment of a 3MLCT emission has been supported by EHMO studies.
Persistent Identifierhttp://hdl.handle.net/10722/167674
ISSN
1470-479X
ISI Accession Number ID
WOS:000169158500018
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorChu, BWKen_US
dc.contributor.authorKo, CCen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:09:50Z-
dc.date.available2012-10-08T03:09:50Z-
dc.date.issued2001en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 2001 n. 12, p. 1911-1919en_US
dc.identifier.issn1470-479Xen_US
dc.identifier.urihttp://hdl.handle.net/10722/167674-
dc.description.abstractA series of ruthenium(II) orthometallated aminocarbene complexes have been synthesized and characterized. Their electrochemistry, electronic absorption, emission, and the crystal structures of [Ru(phen) 2{=C(CH 2Ph)NHC 6H 4}]CF 3SO 3, [Ru(bpy) 2{=C(CH 2Ph)NMeC 6H 4}]PF 6 and [Ru(bpy) 2{=C(CH 2C 4H 3S)NHC 6H 4}]CF 3SO 3 have been studied. The nature of the electronic transitions and the origin of the emission are discussed and an assignment of a 3MLCT emission has been supported by EHMO studies.en_US
dc.languageengen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleSynthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligandsen_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/B100696G-
dc.identifier.scopuseid_2-s2.0-0034743192en_US
dc.identifier.hkuros62507-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0034743192&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue12en_US
dc.identifier.spage1911en_US
dc.identifier.epage1919en_US
dc.identifier.isiWOS:000169158500018-
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridChu, BWK=35209639800en_US
dc.identifier.scopusauthoridKo, CC=35210609800en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US
dc.identifier.issnl1470-479X-

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