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Article: Synthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands
Title | Synthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands |
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Authors | |
Issue Date | 2001 |
Citation | Journal Of The Chemical Society, Dalton Transactions, 2001 n. 12, p. 1911-1919 How to Cite? |
Abstract | A series of ruthenium(II) orthometallated aminocarbene complexes have been synthesized and characterized. Their electrochemistry, electronic absorption, emission, and the crystal structures of [Ru(phen) 2{=C(CH 2Ph)NHC 6H 4}]CF 3SO 3, [Ru(bpy) 2{=C(CH 2Ph)NMeC 6H 4}]PF 6 and [Ru(bpy) 2{=C(CH 2C 4H 3S)NHC 6H 4}]CF 3SO 3 have been studied. The nature of the electronic transitions and the origin of the emission are discussed and an assignment of a 3MLCT emission has been supported by EHMO studies. |
Persistent Identifier | http://hdl.handle.net/10722/167674 |
ISSN | |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Yam, VWW | en_US |
dc.contributor.author | Chu, BWK | en_US |
dc.contributor.author | Ko, CC | en_US |
dc.contributor.author | Cheung, KK | en_US |
dc.date.accessioned | 2012-10-08T03:09:50Z | - |
dc.date.available | 2012-10-08T03:09:50Z | - |
dc.date.issued | 2001 | en_US |
dc.identifier.citation | Journal Of The Chemical Society, Dalton Transactions, 2001 n. 12, p. 1911-1919 | en_US |
dc.identifier.issn | 1470-479X | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167674 | - |
dc.description.abstract | A series of ruthenium(II) orthometallated aminocarbene complexes have been synthesized and characterized. Their electrochemistry, electronic absorption, emission, and the crystal structures of [Ru(phen) 2{=C(CH 2Ph)NHC 6H 4}]CF 3SO 3, [Ru(bpy) 2{=C(CH 2Ph)NMeC 6H 4}]PF 6 and [Ru(bpy) 2{=C(CH 2C 4H 3S)NHC 6H 4}]CF 3SO 3 have been studied. The nature of the electronic transitions and the origin of the emission are discussed and an assignment of a 3MLCT emission has been supported by EHMO studies. | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | Journal of the Chemical Society, Dalton Transactions | en_US |
dc.title | Synthesis, structure, luminescence and electrochemical studies of a novel class of ruthenium(II) polypyridine complexes with orthometallated aminocarbene ligands | en_US |
dc.type | Article | en_US |
dc.identifier.email | Yam, VWW:wwyam@hku.hk | en_US |
dc.identifier.authority | Yam, VWW=rp00822 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1039/B100696G | - |
dc.identifier.scopus | eid_2-s2.0-0034743192 | en_US |
dc.identifier.hkuros | 62507 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0034743192&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.issue | 12 | en_US |
dc.identifier.spage | 1911 | en_US |
dc.identifier.epage | 1919 | en_US |
dc.identifier.isi | WOS:000169158500018 | - |
dc.identifier.scopusauthorid | Yam, VWW=18539304700 | en_US |
dc.identifier.scopusauthorid | Chu, BWK=35209639800 | en_US |
dc.identifier.scopusauthorid | Ko, CC=35210609800 | en_US |
dc.identifier.scopusauthorid | Cheung, KK=7402406613 | en_US |
dc.identifier.issnl | 1470-479X | - |