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Article: Oxidative cleavage of aryl oxazolines using Methyl(trifluoromethyI)dioxirane generated in situ

TitleOxidative cleavage of aryl oxazolines using Methyl(trifluoromethyI)dioxirane generated in situ
Authors
Yang, DYip, YCWang, XC
Issue Date1997
PublisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetlet
Citation
Tetrahedron Letters, 1997, v. 38 n. 40, p. 7083-7086 How to Cite?
DOI: http://dx.doi.org/10.1016/S0040-4039(97)01654-7
AbstractOxidative cleavage of aryl oxazoline 2 using methyl(trifluoromethyl)dioxirane la generated in situ provides the intermediate nitro-ester 8, which undergoes a basic hydrolysis to furnish benzoic acid 11. Even the hindered oxazoline 7 can be cleaved smoothly to afford 3,3'-dimethyl-2,2'-diphenic acid 16. All substituted benzoic acids 11-16 can be isolated in excellent yields (80-95 %).
Persistent Identifierhttp://hdl.handle.net/10722/167563
ISSN
0040-4039
2023 Impact Factor: 1.5
2023 SCImago Journal Rankings: 0.323
ISI Accession Number ID
WOS:A1997XZ36400035
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorYang, Den_US
dc.contributor.authorYip, YCen_US
dc.contributor.authorWang, XCen_US
dc.date.accessioned2012-10-08T03:08:32Z-
dc.date.available2012-10-08T03:08:32Z-
dc.date.issued1997en_US
dc.identifier.citationTetrahedron Letters, 1997, v. 38 n. 40, p. 7083-7086en_US
dc.identifier.issn0040-4039en_US
dc.identifier.urihttp://hdl.handle.net/10722/167563-
dc.description.abstractOxidative cleavage of aryl oxazoline 2 using methyl(trifluoromethyl)dioxirane la generated in situ provides the intermediate nitro-ester 8, which undergoes a basic hydrolysis to furnish benzoic acid 11. Even the hindered oxazoline 7 can be cleaved smoothly to afford 3,3'-dimethyl-2,2'-diphenic acid 16. All substituted benzoic acids 11-16 can be isolated in excellent yields (80-95 %).en_US
dc.languageengen_US
dc.publisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetleten_US
dc.relation.ispartofTetrahedron Lettersen_US
dc.titleOxidative cleavage of aryl oxazolines using Methyl(trifluoromethyI)dioxirane generated in situen_US
dc.typeArticleen_US
dc.identifier.emailYang, D:yangdan@hku.hken_US
dc.identifier.authorityYang, D=rp00825en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0040-4039(97)01654-7en_US
dc.identifier.scopuseid_2-s2.0-0030823864en_US
dc.identifier.hkuros31695-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0030823864&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume38en_US
dc.identifier.issue40en_US
dc.identifier.spage7083en_US
dc.identifier.epage7086en_US
dc.identifier.isiWOS:A1997XZ36400035-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridYang, D=7404800756en_US
dc.identifier.scopusauthoridYip, YC=7005596386en_US
dc.identifier.scopusauthoridWang, XC=9744761800en_US
dc.identifier.issnl0040-4039-

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