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Article: Novel ruthenium(V) dioxo complexes: Synthesis, characterization, and reactivity of trans-[RuV(tmc)(O)2]ClO4 (tmc=1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

TitleNovel ruthenium(V) dioxo complexes: Synthesis, characterization, and reactivity of trans-[RuV(tmc)(O)2]ClO4 (tmc=1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)
Authors
Che, CMWong, KY
Issue Date1986
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1986 n. 3, p. 229-230 How to Cite?
DOI: http://dx.doi.org/10.1039/C39860000229
Abstracttrans-[RuV(tmc)(O)2]ClO4 (tmc=1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been generated by electrochemical reduction of trans-[RuVI(tmc)(O) 2](ClO4)2 in acetonitrile; it is paramagnetic (μeff.=1.98 μB) and rapidly disproportionates into trans-[RuVI(tmc)(O)2]2+ and trans-[Ru IV(tmc)(O)(OH2)]2+ upon dissolution in aqueous acidic solution.
Persistent Identifierhttp://hdl.handle.net/10722/167414
ISSN
0022-4936
ISI Accession Number ID
WOS:A1986A128100027

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorWong, KYen_US
dc.date.accessioned2012-10-08T03:06:40Z-
dc.date.available2012-10-08T03:06:40Z-
dc.date.issued1986en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1986 n. 3, p. 229-230en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/167414-
dc.description.abstracttrans-[RuV(tmc)(O)2]ClO4 (tmc=1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been generated by electrochemical reduction of trans-[RuVI(tmc)(O) 2](ClO4)2 in acetonitrile; it is paramagnetic (μeff.=1.98 μB) and rapidly disproportionates into trans-[RuVI(tmc)(O)2]2+ and trans-[Ru IV(tmc)(O)(OH2)]2+ upon dissolution in aqueous acidic solution.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleNovel ruthenium(V) dioxo complexes: Synthesis, characterization, and reactivity of trans-[RuV(tmc)(O)2]ClO4 (tmc=1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39860000229en_US
dc.identifier.scopuseid_2-s2.0-0013406180en_US
dc.identifier.issue3en_US
dc.identifier.spage229en_US
dc.identifier.epage230en_US
dc.identifier.isiWOS:A1986A128100027-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridWong, KY=7404760030en_US
dc.identifier.issnl0022-4936-

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