File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1016/S0277-5387(00)88212-1
- Scopus: eid_2-s2.0-0013020802
- WOS: WOS:A1993LE55100014
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: X-ray structure and spectroscopic properties of platinum(II) complexes of 1,1′-biisoquinoline
Title | X-ray structure and spectroscopic properties of platinum(II) complexes of 1,1′-biisoquinoline |
---|---|
Authors | |
Issue Date | 1993 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
Citation | Polyhedron, 1993, v. 12 n. 10, p. 1201-1207 How to Cite? |
Abstract | Three plantinum(II) complexes of biq (biq = 1,1′-biisoquinoline), [Pt(biq)Cl2], [Pt(biq)(py)3](ClO4)2 (py = pyridine) and [Pt(biq)(dapy)3](ClO4)2 [dapy = 4-(dimethylamino)pyridine] were prepared. Using 1H NMR spectroscopy and X-ray crystallography, biq in the former complex was found to be bidentate and in the two latter complexes monodentate. Dihedral angles between the two isoquinoline rings were determined to be 35.18° and 41.12° in [Pt(biq)Cl2] and 77.61° in [Pt(biq)(dapy)3](ClO4)2. The crystal structure of [Pt(biq)Cl2] is the first example of η2-μ1 biq complexes with a five-membered chelating ring. Weak intramolecular π-π stacking occurs in the solid phase of [Pt(biq)(dapy)3](ClO4)2. © 1993. |
Persistent Identifier | http://hdl.handle.net/10722/167409 |
ISSN | 2023 Impact Factor: 2.4 2023 SCImago Journal Rankings: 0.379 |
ISI Accession Number ID |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cheng, LK | en_US |
dc.contributor.author | Yeung, KS | en_US |
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Cheng, MC | en_US |
dc.contributor.author | Wang, Y | en_US |
dc.date.accessioned | 2012-10-08T03:06:37Z | - |
dc.date.available | 2012-10-08T03:06:37Z | - |
dc.date.issued | 1993 | en_US |
dc.identifier.citation | Polyhedron, 1993, v. 12 n. 10, p. 1201-1207 | en_US |
dc.identifier.issn | 0277-5387 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167409 | - |
dc.description.abstract | Three plantinum(II) complexes of biq (biq = 1,1′-biisoquinoline), [Pt(biq)Cl2], [Pt(biq)(py)3](ClO4)2 (py = pyridine) and [Pt(biq)(dapy)3](ClO4)2 [dapy = 4-(dimethylamino)pyridine] were prepared. Using 1H NMR spectroscopy and X-ray crystallography, biq in the former complex was found to be bidentate and in the two latter complexes monodentate. Dihedral angles between the two isoquinoline rings were determined to be 35.18° and 41.12° in [Pt(biq)Cl2] and 77.61° in [Pt(biq)(dapy)3](ClO4)2. The crystal structure of [Pt(biq)Cl2] is the first example of η2-μ1 biq complexes with a five-membered chelating ring. Weak intramolecular π-π stacking occurs in the solid phase of [Pt(biq)(dapy)3](ClO4)2. © 1993. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly | en_US |
dc.relation.ispartof | Polyhedron | en_US |
dc.title | X-ray structure and spectroscopic properties of platinum(II) complexes of 1,1′-biisoquinoline | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/S0277-5387(00)88212-1 | - |
dc.identifier.scopus | eid_2-s2.0-0013020802 | en_US |
dc.identifier.volume | 12 | en_US |
dc.identifier.issue | 10 | en_US |
dc.identifier.spage | 1201 | en_US |
dc.identifier.epage | 1207 | en_US |
dc.identifier.isi | WOS:A1993LE55100014 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Cheng, LK=7403337077 | en_US |
dc.identifier.scopusauthorid | Yeung, KS=36775309100 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Cheng, MC=13307876400 | en_US |
dc.identifier.scopusauthorid | Wang, Y=36072665800 | en_US |
dc.identifier.issnl | 0277-5387 | - |