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Article: Synthesis and spectroscopic studies of manganese porphyrin-thiolate complexes

TitleSynthesis and spectroscopic studies of manganese porphyrin-thiolate complexes
Authors
Mu, LHuang, JZhou, YShen, P
KeywordsManganese Porphyrin Thiolate
Nmr
Synthesis
Uv-Vis
Issue Date1997
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1997, v. 16 n. 16, p. 2885-2888 How to Cite?
DOI: http://dx.doi.org/10.1016/S0277-5387(96)00604-3
AbstractThe synthesis and spectroscopic characterization of four manganese(III) porphyrin thiolates are reported. The investigated compounds are represented by (TPP)Mn(SR), where TPP is the dianion of tetraphenylporhyrin and R is C6H5, C6H4(p-NO2), Et2NCS and C4H8NCS. Each complex was characterized by UV-vis and 1H NMR spectroscopy. The effects of axial ligands on the UV-vis spectra of synthesized manganese porphyrin complexes is discussed and proton isotropic shifts are shown to be predominantly contact in origin, reflecting extensive porphyrin-to-metal π bonding. © 1997 Elsevier Science Ltd.
Persistent Identifierhttp://hdl.handle.net/10722/167390
ISSN
0277-5387
2023 Impact Factor: 2.4
2023 SCImago Journal Rankings: 0.379
ISI Accession Number ID
WOS:A1997XC47600027
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorMu, Len_US
dc.contributor.authorHuang, Jen_US
dc.contributor.authorZhou, Yen_US
dc.contributor.authorShen, Pen_US
dc.date.accessioned2012-10-08T03:06:24Z-
dc.date.available2012-10-08T03:06:24Z-
dc.date.issued1997en_US
dc.identifier.citationPolyhedron, 1997, v. 16 n. 16, p. 2885-2888en_US
dc.identifier.issn0277-5387en_US
dc.identifier.urihttp://hdl.handle.net/10722/167390-
dc.description.abstractThe synthesis and spectroscopic characterization of four manganese(III) porphyrin thiolates are reported. The investigated compounds are represented by (TPP)Mn(SR), where TPP is the dianion of tetraphenylporhyrin and R is C6H5, C6H4(p-NO2), Et2NCS and C4H8NCS. Each complex was characterized by UV-vis and 1H NMR spectroscopy. The effects of axial ligands on the UV-vis spectra of synthesized manganese porphyrin complexes is discussed and proton isotropic shifts are shown to be predominantly contact in origin, reflecting extensive porphyrin-to-metal π bonding. © 1997 Elsevier Science Ltd.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_US
dc.relation.ispartofPolyhedronen_US
dc.subjectManganese Porphyrin Thiolateen_US
dc.subjectNmren_US
dc.subjectSynthesisen_US
dc.subjectUv-Visen_US
dc.titleSynthesis and spectroscopic studies of manganese porphyrin-thiolate complexesen_US
dc.typeArticleen_US
dc.identifier.emailHuang, J:jshuang@hkucc.hku.hken_US
dc.identifier.authorityHuang, J=rp00709en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0277-5387(96)00604-3-
dc.identifier.scopuseid_2-s2.0-0006501230en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0006501230&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume16en_US
dc.identifier.issue16en_US
dc.identifier.spage2885en_US
dc.identifier.epage2888en_US
dc.identifier.isiWOS:A1997XC47600027-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridMu, L=7005437525en_US
dc.identifier.scopusauthoridHuang, J=7407192639en_US
dc.identifier.scopusauthoridZhou, Y=8047648700en_US
dc.identifier.scopusauthoridShen, P=7201767682en_US
dc.identifier.issnl0277-5387-

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