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- Publisher Website: 10.1016/S0020-1693(00)82958-8
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Article: Low-spin iron(III) complexes of a tetradentate bis-amide ligand and X-ray crystal structure of trans-[Fe(bpc)(1-MeIm)2]ClO4 (H2bpc=4, 5-dichloro-1, 2-bis(2-pyridinecarboxamido)benzene; 1-MeIm=1-methylimidazole)
Title | Low-spin iron(III) complexes of a tetradentate bis-amide ligand and X-ray crystal structure of trans-[Fe(bpc)(1-MeIm)2]ClO4 (H2bpc=4, 5-dichloro-1, 2-bis(2-pyridinecarboxamido)benzene; 1-MeIm=1-methylimidazole) |
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Authors | |
Issue Date | 1992 |
Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica |
Citation | Inorganica Chimica Acta, 1992, v. 196 n. 1, p. 43-48 How to Cite? |
Abstract | A series of low-spin iron(III) complexes [Fe(bpc)(L)2]+ (H2bpc=4,5-dichloro-1,2-bis(2-pyridinecarboxamido)- benzene; LBu3P, Im, 1-MeIm, tBupy) have been synthesized. These iron complexes display reversible one-electron oxidation and reduction couples. The stable one-electron-oxidized species [Fe(bpc)(Bu3P)2]2+ has been generated electrochemically. The complex trans-[Fe(bpc)(1-MeIm)2](ClO4) has been characterized by X-ray crystallography: space group P1; a=8.425(1), b=9.512(1), c=18.413(19) Å; α=96.91(4), β=95.83(4), γ=90.44(1)°; V=1457(2) Å3; Z=2. © 1992. |
Persistent Identifier | http://hdl.handle.net/10722/167369 |
ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.386 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Leung, WH | en_US |
dc.contributor.author | Li, CK | en_US |
dc.contributor.author | HeiYing, C | en_US |
dc.contributor.author | ShieMing, P | en_US |
dc.date.accessioned | 2012-10-08T03:06:08Z | - |
dc.date.available | 2012-10-08T03:06:08Z | - |
dc.date.issued | 1992 | en_US |
dc.identifier.citation | Inorganica Chimica Acta, 1992, v. 196 n. 1, p. 43-48 | en_US |
dc.identifier.issn | 0020-1693 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167369 | - |
dc.description.abstract | A series of low-spin iron(III) complexes [Fe(bpc)(L)2]+ (H2bpc=4,5-dichloro-1,2-bis(2-pyridinecarboxamido)- benzene; LBu3P, Im, 1-MeIm, tBupy) have been synthesized. These iron complexes display reversible one-electron oxidation and reduction couples. The stable one-electron-oxidized species [Fe(bpc)(Bu3P)2]2+ has been generated electrochemically. The complex trans-[Fe(bpc)(1-MeIm)2](ClO4) has been characterized by X-ray crystallography: space group P1; a=8.425(1), b=9.512(1), c=18.413(19) Å; α=96.91(4), β=95.83(4), γ=90.44(1)°; V=1457(2) Å3; Z=2. © 1992. | en_US |
dc.language | eng | en_US |
dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica | en_US |
dc.relation.ispartof | Inorganica Chimica Acta | en_US |
dc.title | Low-spin iron(III) complexes of a tetradentate bis-amide ligand and X-ray crystal structure of trans-[Fe(bpc)(1-MeIm)2]ClO4 (H2bpc=4, 5-dichloro-1, 2-bis(2-pyridinecarboxamido)benzene; 1-MeIm=1-methylimidazole) | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/S0020-1693(00)82958-8 | - |
dc.identifier.scopus | eid_2-s2.0-0002630035 | en_US |
dc.identifier.volume | 196 | en_US |
dc.identifier.issue | 1 | en_US |
dc.identifier.spage | 43 | en_US |
dc.identifier.epage | 48 | en_US |
dc.identifier.isi | WOS:A1992JL78200006 | - |
dc.publisher.place | Netherlands | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Leung, WH=7201504510 | en_US |
dc.identifier.scopusauthorid | Li, CK=8714186500 | en_US |
dc.identifier.scopusauthorid | HeiYing, C=24320664200 | en_US |
dc.identifier.scopusauthorid | ShieMing, P=24286339000 | en_US |
dc.identifier.issnl | 0020-1693 | - |