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- Publisher Website: 10.1002/(SICI)1097-4555(199911)30:11<987::AID-JRS471>3.0.CO;2-3
- Scopus: eid_2-s2.0-0001768169
- WOS: WOS:000083721900003
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Article: Resonance Raman intensity analysis investigation of metal-metal bonded transitions: An examination of the1A2u ← 1A1g (5dσ* → 6pσ) transition of Pt2(P2O5H2)4 4-
Title | Resonance Raman intensity analysis investigation of metal-metal bonded transitions: An examination of the1A2u ← 1A1g (5dσ* → 6pσ) transition of Pt2(P2O5H2)4 4- |
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Authors | |
Issue Date | 1999 |
Publisher | John Wiley & Sons Ltd. The Journal's web site is located at http://www3.interscience.wiley.com/cgi-bin/jhome/3420 |
Citation | Journal Of Raman Spectroscopy, 1999, v. 30 n. 11, p. 987-993 How to Cite? |
Abstract | A preliminary resonance Raman intensity analysis study of the 1A2u ← 1A1g (5dσ* → 6pσ) transition of (n-Bu4N)4[Pt2(P2O5H 2)4] in acetonitrile solution at room temperature is reported. The absolute resonance Raman and absorption intensities were simultaneously simulated using wavepacket calculations and a simple model. The best fit parameters indicate that the Pt - Pt bond length changes by about 0.225 Å in the initially excited 1A2u state relative to the ground state. This is in good agreement with previous studies on the vibronically structured absorption and emission spectra of low-temperature crystalline (n-Bu4N)4[Pt2(P2O5H 2)4] which suggested that the Pt - Pt bond length changes by about 0.21 Å in the 1,3A2u states. The resonance Raman intensity analysis demonstrated here can be generally applied to metal-metal bonded electronic transitions for compounds and sample conditions (such as room temperature liquids for many samples) which do not exhibit any vibronic structure. Copyright © 1999 John Wiley & Sons, Ltd. |
Persistent Identifier | http://hdl.handle.net/10722/167364 |
ISSN | 2023 Impact Factor: 2.4 2023 SCImago Journal Rankings: 0.532 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Leung, KH | en_US |
dc.contributor.author | Phillips, DL | en_US |
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Miskowski, VM | en_US |
dc.date.accessioned | 2012-10-08T03:06:04Z | - |
dc.date.available | 2012-10-08T03:06:04Z | - |
dc.date.issued | 1999 | en_US |
dc.identifier.citation | Journal Of Raman Spectroscopy, 1999, v. 30 n. 11, p. 987-993 | en_US |
dc.identifier.issn | 0377-0486 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167364 | - |
dc.description.abstract | A preliminary resonance Raman intensity analysis study of the 1A2u ← 1A1g (5dσ* → 6pσ) transition of (n-Bu4N)4[Pt2(P2O5H 2)4] in acetonitrile solution at room temperature is reported. The absolute resonance Raman and absorption intensities were simultaneously simulated using wavepacket calculations and a simple model. The best fit parameters indicate that the Pt - Pt bond length changes by about 0.225 Å in the initially excited 1A2u state relative to the ground state. This is in good agreement with previous studies on the vibronically structured absorption and emission spectra of low-temperature crystalline (n-Bu4N)4[Pt2(P2O5H 2)4] which suggested that the Pt - Pt bond length changes by about 0.21 Å in the 1,3A2u states. The resonance Raman intensity analysis demonstrated here can be generally applied to metal-metal bonded electronic transitions for compounds and sample conditions (such as room temperature liquids for many samples) which do not exhibit any vibronic structure. Copyright © 1999 John Wiley & Sons, Ltd. | en_US |
dc.language | eng | en_US |
dc.publisher | John Wiley & Sons Ltd. The Journal's web site is located at http://www3.interscience.wiley.com/cgi-bin/jhome/3420 | en_US |
dc.relation.ispartof | Journal of Raman Spectroscopy | en_US |
dc.title | Resonance Raman intensity analysis investigation of metal-metal bonded transitions: An examination of the1A2u ← 1A1g (5dσ* → 6pσ) transition of Pt2(P2O5H2)4 4- | en_US |
dc.type | Article | en_US |
dc.identifier.email | Phillips, DL:phillips@hku.hk | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Phillips, DL=rp00770 | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1002/(SICI)1097-4555(199911)30:11<987::AID-JRS471>3.0.CO;2-3 | - |
dc.identifier.scopus | eid_2-s2.0-0001768169 | en_US |
dc.identifier.hkuros | 50351 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0001768169&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 30 | en_US |
dc.identifier.issue | 11 | en_US |
dc.identifier.spage | 987 | en_US |
dc.identifier.epage | 993 | en_US |
dc.identifier.isi | WOS:000083721900003 | - |
dc.publisher.place | United Kingdom | en_US |
dc.identifier.scopusauthorid | Leung, KH=7401860609 | en_US |
dc.identifier.scopusauthorid | Phillips, DL=7404519365 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Miskowski, VM=6603008214 | en_US |
dc.identifier.issnl | 0377-0486 | - |