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Article: Synthesis, emission, and molecular orbital studies of luminescent hafnium thiolate complexes. Crystal structures of (η5-C5Me5)2Hf(SR)2 (R = nBu, C6H5, C6H4OMe-p)

TitleSynthesis, emission, and molecular orbital studies of luminescent hafnium thiolate complexes. Crystal structures of (η5-C5Me5)2Hf(SR)2 (R = nBu, C6H5, C6H4OMe-p)
Authors
Yam, VWWQi, GZCheung, KK
Issue Date1998
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 1998, v. 17 n. 25, p. 5448-5453 How to Cite?
DOI: http://dx.doi.org/10.1021/om980602f
AbstractA series of luminescent hafnium thiolate complexes (η5C5Me5)2Hf(SR)2 (R = nBu, C6H5, C6H4OMe-p, C6H4 tBu-p) have been synthesized by the reaction of (η5-C5Me5)2HfCl2 with LiSR and shown to exhibit rich luminescence behavior. The crystal structures of (η5-C5Me5)2Hf-(S nBu)2, (η5-C5Me5)2Hf(SC 6H5)2, and (η5-C5Me5)2Hf(SC 6H4OMe-p)2 have been determined. Fenske-Hall molecular orbital calculations on the hafnium thiolate complexes reveal a thiolate-based HOMO and a LUMO that is mainly composed of hafnium d character. © 1998 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/167315
ISSN
0276-7333
2023 Impact Factor: 2.5
2023 SCImago Journal Rankings: 0.654
ISI Accession Number ID
WOS:000077517600003
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorQi, GZen_US
dc.contributor.authorCheung, KKen_US
dc.date.accessioned2012-10-08T03:05:35Z-
dc.date.available2012-10-08T03:05:35Z-
dc.date.issued1998en_US
dc.identifier.citationOrganometallics, 1998, v. 17 n. 25, p. 5448-5453en_US
dc.identifier.issn0276-7333en_US
dc.identifier.urihttp://hdl.handle.net/10722/167315-
dc.description.abstractA series of luminescent hafnium thiolate complexes (η5C5Me5)2Hf(SR)2 (R = nBu, C6H5, C6H4OMe-p, C6H4 tBu-p) have been synthesized by the reaction of (η5-C5Me5)2HfCl2 with LiSR and shown to exhibit rich luminescence behavior. The crystal structures of (η5-C5Me5)2Hf-(S nBu)2, (η5-C5Me5)2Hf(SC 6H5)2, and (η5-C5Me5)2Hf(SC 6H4OMe-p)2 have been determined. Fenske-Hall molecular orbital calculations on the hafnium thiolate complexes reveal a thiolate-based HOMO and a LUMO that is mainly composed of hafnium d character. © 1998 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_US
dc.relation.ispartofOrganometallicsen_US
dc.titleSynthesis, emission, and molecular orbital studies of luminescent hafnium thiolate complexes. Crystal structures of (η5-C5Me5)2Hf(SR)2 (R = nBu, C6H5, C6H4OMe-p)en_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/om980602f-
dc.identifier.scopuseid_2-s2.0-0001005494en_US
dc.identifier.hkuros39871-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0001005494&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume17en_US
dc.identifier.issue25en_US
dc.identifier.spage5448en_US
dc.identifier.epage5453en_US
dc.identifier.isiWOS:000077517600003-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridQi, GZ=8300870200en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US
dc.identifier.issnl0276-7333-

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