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Article: Six- and seven-coordinated manganese(II) complexes of quaterpyridine. Synthesis, X-ray crystal structure and catalyst for alkene epoxidation

TitleSix- and seven-coordinated manganese(II) complexes of quaterpyridine. Synthesis, X-ray crystal structure and catalyst for alkene epoxidation
Authors
Issue Date1993
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1993, v. 12 n. 18, p. 2169-2173 How to Cite?
AbstractReaction of Mn(ClO4)2 · xH2O and Mn(CH3CO2)3 · xH2O with 2.2′ : 6′,2″ : 6″,2′″-quaterpyridine (QP) in acetonitrile or methanol gave the complexes [Mn(QP)(H2O)2] (ClO4)2 and [Mn(QP)(CH3CO2)(H2O)](ClO4), respectively. X-ray crystal structure determination revealed that the manganese atom is six-coordinated in the former, but seven-coordinated in the latter. Both complexes catalysed oxidation of alkenes by PhIO. © 1993.
Persistent Identifierhttp://hdl.handle.net/10722/167293
ISSN
2021 Impact Factor: 2.975
2020 SCImago Journal Rankings: 0.496
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChan, CWen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorPeng, SMen_US
dc.date.accessioned2012-10-08T03:05:21Z-
dc.date.available2012-10-08T03:05:21Z-
dc.date.issued1993en_US
dc.identifier.citationPolyhedron, 1993, v. 12 n. 18, p. 2169-2173en_US
dc.identifier.issn0277-5387en_US
dc.identifier.urihttp://hdl.handle.net/10722/167293-
dc.description.abstractReaction of Mn(ClO4)2 · xH2O and Mn(CH3CO2)3 · xH2O with 2.2′ : 6′,2″ : 6″,2′″-quaterpyridine (QP) in acetonitrile or methanol gave the complexes [Mn(QP)(H2O)2] (ClO4)2 and [Mn(QP)(CH3CO2)(H2O)](ClO4), respectively. X-ray crystal structure determination revealed that the manganese atom is six-coordinated in the former, but seven-coordinated in the latter. Both complexes catalysed oxidation of alkenes by PhIO. © 1993.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_US
dc.relation.ispartofPolyhedronen_US
dc.titleSix- and seven-coordinated manganese(II) complexes of quaterpyridine. Synthesis, X-ray crystal structure and catalyst for alkene epoxidationen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/S0277-5387(00)88253-4-
dc.identifier.scopuseid_2-s2.0-0000709237en_US
dc.identifier.volume12en_US
dc.identifier.issue18en_US
dc.identifier.spage2169en_US
dc.identifier.epage2173en_US
dc.identifier.isiWOS:A1993MB63900001-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridChan, CW=7404814723en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridPeng, SM=35464852200en_US
dc.identifier.issnl0277-5387-

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