File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1021/ic980256u
- Scopus: eid_2-s2.0-0000601741
- PMID: 11670787
- WOS: WOS:000077839100006
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Synthesis, Spectroscopic Properties, and Reactivities of Bis(tosylimido)osmium(VI) Porphyrin Complexes. X-ray Crystal Structure of [OsVI(TPP)(NSO2C6H4-pCH 3)2] (TPP = Tetraphenylporphyrinato)
Title | Synthesis, Spectroscopic Properties, and Reactivities of Bis(tosylimido)osmium(VI) Porphyrin Complexes. X-ray Crystal Structure of [OsVI(TPP)(NSO2C6H4-pCH 3)2] (TPP = Tetraphenylporphyrinato) |
---|---|
Authors | |
Issue Date | 1998 |
Publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic |
Citation | Inorganic Chemistry, 1998, v. 37 n. 26, p. 6564-6567 How to Cite? |
Abstract | The bis(tosylimido)osmium(VI) porphyrins [OsVI(Por)(NTs)2] [Por = tetraphenylporphyrinato (TPP), meso-tetrakis(p-tolyl)porphyrinato (TTP), meso-tetrakis(4-chlorophenyl)porphyrinato (4-Cl-TPP), weso-tetrakis(4-methoxyphenyl)porphyrinato (4-MeO-TPP); Ts = tosyl] were prepared from the reactions of [OsII(Por)(CO)(MeOH)] with excess PhI=NTs in dichloromethane. The X-ray crystal structure of [OsVI(TPP)(NTs)2] has been determined. Crystal data for [OsVI(TPP)(NTs)2]: triclinic, space group P1̄ (No. 2), a = 10.836(3) Å, b = 12.067(4) Å, c = 19.647(6) Å, α = 94.05(3)°, β= 93.88(3)°, γ = 104.65(3)°, V = 2469(1) Å3, Z = 2, R (Rw) = 0.030 (0.038), goodness-of-fit =1.19. The mean Os=NTs distance is 1.800 Å. The Os-N-S angles average 155.8°. Reaction of [OsVI(TPP)(NTs)2] with triphenylphosphine gives Ph3P=NTs and [OsII(TPP)(PPh3)2]. |
Persistent Identifier | http://hdl.handle.net/10722/167282 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 0.928 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Au, SM | en_US |
dc.contributor.author | Fung, WH | en_US |
dc.contributor.author | Huang, JS | en_US |
dc.contributor.author | Cheung, KK | en_US |
dc.contributor.author | Che, CM | en_US |
dc.date.accessioned | 2012-10-08T03:05:13Z | - |
dc.date.available | 2012-10-08T03:05:13Z | - |
dc.date.issued | 1998 | en_US |
dc.identifier.citation | Inorganic Chemistry, 1998, v. 37 n. 26, p. 6564-6567 | en_US |
dc.identifier.issn | 0020-1669 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167282 | - |
dc.description.abstract | The bis(tosylimido)osmium(VI) porphyrins [OsVI(Por)(NTs)2] [Por = tetraphenylporphyrinato (TPP), meso-tetrakis(p-tolyl)porphyrinato (TTP), meso-tetrakis(4-chlorophenyl)porphyrinato (4-Cl-TPP), weso-tetrakis(4-methoxyphenyl)porphyrinato (4-MeO-TPP); Ts = tosyl] were prepared from the reactions of [OsII(Por)(CO)(MeOH)] with excess PhI=NTs in dichloromethane. The X-ray crystal structure of [OsVI(TPP)(NTs)2] has been determined. Crystal data for [OsVI(TPP)(NTs)2]: triclinic, space group P1̄ (No. 2), a = 10.836(3) Å, b = 12.067(4) Å, c = 19.647(6) Å, α = 94.05(3)°, β= 93.88(3)°, γ = 104.65(3)°, V = 2469(1) Å3, Z = 2, R (Rw) = 0.030 (0.038), goodness-of-fit =1.19. The mean Os=NTs distance is 1.800 Å. The Os-N-S angles average 155.8°. Reaction of [OsVI(TPP)(NTs)2] with triphenylphosphine gives Ph3P=NTs and [OsII(TPP)(PPh3)2]. | en_US |
dc.language | eng | en_US |
dc.publisher | American Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic | en_US |
dc.relation.ispartof | Inorganic Chemistry | en_US |
dc.title | Synthesis, Spectroscopic Properties, and Reactivities of Bis(tosylimido)osmium(VI) Porphyrin Complexes. X-ray Crystal Structure of [OsVI(TPP)(NSO2C6H4-pCH 3)2] (TPP = Tetraphenylporphyrinato) | en_US |
dc.type | Article | en_US |
dc.identifier.email | Huang, JS:jshuang@hkucc.hku.hk | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Huang, JS=rp00709 | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1021/ic980256u | - |
dc.identifier.pmid | 11670787 | - |
dc.identifier.scopus | eid_2-s2.0-0000601741 | en_US |
dc.identifier.hkuros | 40279 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0000601741&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 37 | en_US |
dc.identifier.issue | 26 | en_US |
dc.identifier.spage | 6564 | en_US |
dc.identifier.epage | 6567 | en_US |
dc.identifier.isi | WOS:000077839100006 | - |
dc.publisher.place | United States | en_US |
dc.identifier.scopusauthorid | Au, SM=7005457811 | en_US |
dc.identifier.scopusauthorid | Fung, WH=7102150303 | en_US |
dc.identifier.scopusauthorid | Huang, JS=7407192639 | en_US |
dc.identifier.scopusauthorid | Cheung, KK=7402406613 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.issnl | 0020-1669 | - |