File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1016/0022-0728(91)87079-J
- Scopus: eid_2-s2.0-0000550474
- WOS: WOS:A1991HJ07400016
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: Synthesis and electrocatalytic properties of a cis-diaquo-ruthenium(II) complex with 6,6'-dichloro-2,2'-bipyridine
Title | Synthesis and electrocatalytic properties of a cis-diaquo-ruthenium(II) complex with 6,6'-dichloro-2,2'-bipyridine |
---|---|
Authors | |
Issue Date | 1991 |
Citation | Journal Of Electroanalytical Chemistry, 1991, v. 319 n. 1-2, p. 207-216 How to Cite? |
Abstract | The syntheses of cis-[RuII(6,6'-Cl2bpy)2(OH2) 2(ClO4)2, cis-[RuVI(6,6'-Cl2bpy)2]O)2] ClO4)2 and cis-[RuII(6,6'-Cl2bpy) 2(CH3CN)2](ClO4)2 ·H2O complexes are described. In 0.1 M CF3COOH, cis-[RuII (6,6'-Cl2bpy)2(OH2)2]2+ exhibits two quasi-reversible, two-electron couples at 0.93 and 1.17 V vs. SCE assignable to the cis-[RuVI(6,6'-Cl2bpy)2(O)(OH2 )]2+/cis-[RuII(6,6'-Cl 2bpy)2(OH2)2]2+ and the cis-[RuVI(6,6'-Cl2bpy)2(O)2] 2+/cis- [RuVI(6,6'-Cl2bpy)2(O)(OH2)] 2+ couples, respectively. The formal potentials of both couples shift to more negative values by 60 mV per unit pH change as the pH of the medium is raised. cis-[RuVI (6,6'-Cl2bpy)2(O)2)]2+ generated electrochemically is an active catalyst for the oxidation of alcohols, tetrahydrofuran, dextrose and chloride. Incorporation of cis-[RuII(6,6'-Cl2bpy) 2(OH2)2]2+ into Nafion® films on the electrodes produces electrodes at which the rate of oxidation of organic substrates and chloride ion is enhanced. © 1992. |
Persistent Identifier | http://hdl.handle.net/10722/167280 |
ISSN | |
ISI Accession Number ID |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Wong, KY | en_US |
dc.contributor.author | Lee, WO | en_US |
dc.contributor.author | Che, CM | en_US |
dc.contributor.author | Anson, FC | en_US |
dc.date.accessioned | 2012-10-08T03:05:11Z | - |
dc.date.available | 2012-10-08T03:05:11Z | - |
dc.date.issued | 1991 | en_US |
dc.identifier.citation | Journal Of Electroanalytical Chemistry, 1991, v. 319 n. 1-2, p. 207-216 | en_US |
dc.identifier.issn | 0022-0728 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/167280 | - |
dc.description.abstract | The syntheses of cis-[RuII(6,6'-Cl2bpy)2(OH2) 2(ClO4)2, cis-[RuVI(6,6'-Cl2bpy)2]O)2] ClO4)2 and cis-[RuII(6,6'-Cl2bpy) 2(CH3CN)2](ClO4)2 ·H2O complexes are described. In 0.1 M CF3COOH, cis-[RuII (6,6'-Cl2bpy)2(OH2)2]2+ exhibits two quasi-reversible, two-electron couples at 0.93 and 1.17 V vs. SCE assignable to the cis-[RuVI(6,6'-Cl2bpy)2(O)(OH2 )]2+/cis-[RuII(6,6'-Cl 2bpy)2(OH2)2]2+ and the cis-[RuVI(6,6'-Cl2bpy)2(O)2] 2+/cis- [RuVI(6,6'-Cl2bpy)2(O)(OH2)] 2+ couples, respectively. The formal potentials of both couples shift to more negative values by 60 mV per unit pH change as the pH of the medium is raised. cis-[RuVI (6,6'-Cl2bpy)2(O)2)]2+ generated electrochemically is an active catalyst for the oxidation of alcohols, tetrahydrofuran, dextrose and chloride. Incorporation of cis-[RuII(6,6'-Cl2bpy) 2(OH2)2]2+ into Nafion® films on the electrodes produces electrodes at which the rate of oxidation of organic substrates and chloride ion is enhanced. © 1992. | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | Journal of Electroanalytical Chemistry | en_US |
dc.title | Synthesis and electrocatalytic properties of a cis-diaquo-ruthenium(II) complex with 6,6'-dichloro-2,2'-bipyridine | en_US |
dc.type | Article | en_US |
dc.identifier.email | Che, CM:cmche@hku.hk | en_US |
dc.identifier.authority | Che, CM=rp00670 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.doi | 10.1016/0022-0728(91)87079-J | - |
dc.identifier.scopus | eid_2-s2.0-0000550474 | en_US |
dc.identifier.volume | 319 | en_US |
dc.identifier.issue | 1-2 | en_US |
dc.identifier.spage | 207 | en_US |
dc.identifier.epage | 216 | en_US |
dc.identifier.isi | WOS:A1991HJ07400016 | - |
dc.identifier.scopusauthorid | Wong, KY=37096572700 | en_US |
dc.identifier.scopusauthorid | Lee, WO=7407087172 | en_US |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_US |
dc.identifier.scopusauthorid | Anson, FC=7006393695 | en_US |
dc.identifier.issnl | 0022-0728 | - |