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Article: Resonance Raman spectra of trans and gauche isomers of n-propyl iodide: Evidence for the dependence of photodissociation dynamics on geometrical conformation

TitleResonance Raman spectra of trans and gauche isomers of n-propyl iodide: Evidence for the dependence of photodissociation dynamics on geometrical conformation
Authors
Phillips, DLLawrence, BAValentini, JJ
Issue Date1991
Citation
Journal Of Physical Chemistry, 1991, v. 95 n. 20, p. 7570-7575 How to Cite?
DOI: http://dx.doi.org/10.1021/j100173a004
AbstractGas-phase resonance Raman spectra of trans- and gauche-n-propyl iodide at 266 nm have been obtained. The trans conformation gives more Raman vibrational intensity overall than the gauche conformation and greater intensity in bending modes relative to the C-I stretching mode. The short-time photodissociation dynamics of the trans- and gauche-n-propyl iodide isomers are inferred from these Raman spectra and are discussed in terms of simple models of the photodissociation. The differences in the resonance Raman spectra of the trans and gauche species appear to be the result of different photodissociation dynamics for the two conformers. © 1991 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/167257
ISSN
0022-3654
ISI Accession Number ID
WOS:A1991GH89300004

 

DC FieldValueLanguage
dc.contributor.authorPhillips, DLen_US
dc.contributor.authorLawrence, BAen_US
dc.contributor.authorValentini, JJen_US
dc.date.accessioned2012-10-08T03:04:57Z-
dc.date.available2012-10-08T03:04:57Z-
dc.date.issued1991en_US
dc.identifier.citationJournal Of Physical Chemistry, 1991, v. 95 n. 20, p. 7570-7575en_US
dc.identifier.issn0022-3654en_US
dc.identifier.urihttp://hdl.handle.net/10722/167257-
dc.description.abstractGas-phase resonance Raman spectra of trans- and gauche-n-propyl iodide at 266 nm have been obtained. The trans conformation gives more Raman vibrational intensity overall than the gauche conformation and greater intensity in bending modes relative to the C-I stretching mode. The short-time photodissociation dynamics of the trans- and gauche-n-propyl iodide isomers are inferred from these Raman spectra and are discussed in terms of simple models of the photodissociation. The differences in the resonance Raman spectra of the trans and gauche species appear to be the result of different photodissociation dynamics for the two conformers. © 1991 American Chemical Society.en_US
dc.languageengen_US
dc.relation.ispartofJournal of Physical Chemistryen_US
dc.titleResonance Raman spectra of trans and gauche isomers of n-propyl iodide: Evidence for the dependence of photodissociation dynamics on geometrical conformationen_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/j100173a004-
dc.identifier.scopuseid_2-s2.0-0000190221en_US
dc.identifier.volume95en_US
dc.identifier.issue20en_US
dc.identifier.spage7570en_US
dc.identifier.epage7575en_US
dc.identifier.isiWOS:A1991GH89300004-
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US
dc.identifier.scopusauthoridLawrence, BA=36900494600en_US
dc.identifier.scopusauthoridValentini, JJ=7003875862en_US
dc.identifier.issnl0022-3654-

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