File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: The 3(ππ*) Emission of Cy 3PAu(C≡C) nAuPCy 3 (n = 3, 4). Effect of chain length upon acetylenic 3(ππ*) emission

TitleThe 3(ππ*) Emission of Cy 3PAu(C≡C) nAuPCy 3 (n = 3, 4). Effect of chain length upon acetylenic 3(ππ*) emission
Authors
Lu, WXiang, HFZhu, NChe, CM
Issue Date2002
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 2002, v. 21 n. 11, p. 2343-2346 How to Cite?
DOI: http://dx.doi.org/10.1021/om011087f
AbstractThe synthesis of luminescent Cy 3PAu(C≡C) nAuPCy 3 complexes (n = 3,4) was presented. the complexes featured the dinuclear gold(I) complexes bridged by C 6 2- and C 8 2- rods. The compounds revealed highly vibronic acetylenic 3(ππ*) excited states, due to Au spin-orbital coupling. The absorption band for the π → π* transition was significantly red-shifted when compared to the lowest-energy dipole-allowed transition of the P(C≡C) 4R (R = CN, tBu) series.
Persistent Identifierhttp://hdl.handle.net/10722/154763
ISSN
0276-7333
2023 Impact Factor: 2.5
2023 SCImago Journal Rankings: 0.654
ISI Accession Number ID
WOS:000175734300028
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorLu, Wen_HK
dc.contributor.authorXiang, HFen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2012-08-08T08:30:31Z-
dc.date.available2012-08-08T08:30:31Z-
dc.date.issued2002en_HK
dc.identifier.citationOrganometallics, 2002, v. 21 n. 11, p. 2343-2346en_HK
dc.identifier.issn0276-7333en_HK
dc.identifier.urihttp://hdl.handle.net/10722/154763-
dc.description.abstractThe synthesis of luminescent Cy 3PAu(C≡C) nAuPCy 3 complexes (n = 3,4) was presented. the complexes featured the dinuclear gold(I) complexes bridged by C 6 2- and C 8 2- rods. The compounds revealed highly vibronic acetylenic 3(ππ*) excited states, due to Au spin-orbital coupling. The absorption band for the π → π* transition was significantly red-shifted when compared to the lowest-energy dipole-allowed transition of the P(C≡C) 4R (R = CN, tBu) series.en_HK
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_HK
dc.relation.ispartofOrganometallicsen_HK
dc.titleThe 3(ππ*) Emission of Cy 3PAu(C≡C) nAuPCy 3 (n = 3, 4). Effect of chain length upon acetylenic 3(ππ*) emissionen_HK
dc.typeArticleen_HK
dc.identifier.emailXiang, HF: hfxiang@eee.hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityXiang, HF=rp00196en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/om011087fen_HK
dc.identifier.scopuseid_2-s2.0-0000619922en_HK
dc.identifier.hkuros69078-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0000619922&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume21en_HK
dc.identifier.issue11en_HK
dc.identifier.spage2343en_HK
dc.identifier.epage2346en_HK
dc.identifier.isiWOS:000175734300028-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridLu, W=55277832700en_HK
dc.identifier.scopusauthoridXiang, HF=23065758900en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.issnl0276-7333-

Export via OAI-PMH Interface in XML Formats

OR

Export to Other Non-XML Formats