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Article: Iron-Catalyzed Nitrene Insertion Reaction for Facile Construction of Amide Compounds
Title | Iron-Catalyzed Nitrene Insertion Reaction for Facile Construction of Amide Compounds | ||||||||||||||
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Authors | |||||||||||||||
Keywords | amide C-H insertion catalysis iron nitrene | ||||||||||||||
Issue Date | 2011 | ||||||||||||||
Publisher | Georg Thieme Verlag. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml | ||||||||||||||
Citation | Synlett, 2011 n. 8, p. 1174-1178 How to Cite? | ||||||||||||||
Abstract | A facile method for the construction of amide compounds from aldehydes by an iron-catalyzed nitrene insertion reaction has been developed. Both aryl and aliphatic aldehydes can directly afford the corresponding amides with an iron(II)-terpyridine (tpy) complex formed in situ as catalyst, and PhI=NTs as nitrogen source under mild reaction conditions. An ESI-MS study revealed the formation of [Fe(tpy)NTs)]+ as a reaction intermediate. © Georg Thieme Verlag Stuttgart - New York. | ||||||||||||||
Persistent Identifier | http://hdl.handle.net/10722/135045 | ||||||||||||||
ISSN | 2023 Impact Factor: 1.7 2023 SCImago Journal Rankings: 0.450 | ||||||||||||||
ISI Accession Number ID |
Funding Information: We gratefully acknowledge financial support from The University of Hong Kong (University Development Fund), Hong Kong Research Grants Council (HKU 1/CRF/08), the University Grants Council of HKSAR (Area of Excellence Scheme: AoE 10/01P), CAS-GJHZ200816 and CAS-Croucher Funding Scheme for Joint Laboratory. G.-Q. Chen thanks the Croucher Foundation of Hong Kong for a postgraduate studentship. | ||||||||||||||
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chen, GQ | en_HK |
dc.contributor.author | Xu, ZJ | en_HK |
dc.contributor.author | Liu, Y | en_HK |
dc.contributor.author | Zhou, CY | en_HK |
dc.contributor.author | Che, CM | en_HK |
dc.date.accessioned | 2011-07-27T01:27:07Z | - |
dc.date.available | 2011-07-27T01:27:07Z | - |
dc.date.issued | 2011 | en_HK |
dc.identifier.citation | Synlett, 2011 n. 8, p. 1174-1178 | en_HK |
dc.identifier.issn | 0936-5214 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/135045 | - |
dc.description.abstract | A facile method for the construction of amide compounds from aldehydes by an iron-catalyzed nitrene insertion reaction has been developed. Both aryl and aliphatic aldehydes can directly afford the corresponding amides with an iron(II)-terpyridine (tpy) complex formed in situ as catalyst, and PhI=NTs as nitrogen source under mild reaction conditions. An ESI-MS study revealed the formation of [Fe(tpy)NTs)]+ as a reaction intermediate. © Georg Thieme Verlag Stuttgart - New York. | en_HK |
dc.language | eng | en_US |
dc.publisher | Georg Thieme Verlag. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml | en_HK |
dc.relation.ispartof | Synlett | en_HK |
dc.rights | SYNLETT. Copyright © Georg Thieme Verlag. | - |
dc.subject | amide | en_HK |
dc.subject | C-H insertion | en_HK |
dc.subject | catalysis | en_HK |
dc.subject | iron | en_HK |
dc.subject | nitrene | en_HK |
dc.title | Iron-Catalyzed Nitrene Insertion Reaction for Facile Construction of Amide Compounds | en_HK |
dc.type | Article | en_HK |
dc.identifier.email | Liu, Y:lyg100@hku.hk | en_HK |
dc.identifier.email | Zhou, CY:cyzhou@hku.hk | en_HK |
dc.identifier.email | Che, CM:cmche@hku.hk | en_HK |
dc.identifier.authority | Liu, Y=rp00749 | en_HK |
dc.identifier.authority | Zhou, CY=rp00843 | en_HK |
dc.identifier.authority | Che, CM=rp00670 | en_HK |
dc.description.nature | postprint | - |
dc.identifier.doi | 10.1055/s-0030-1260531 | en_HK |
dc.identifier.scopus | eid_2-s2.0-79955673935 | en_HK |
dc.identifier.hkuros | 188049 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-79955673935&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 8 | en_US |
dc.identifier.issue | 8 | en_HK |
dc.identifier.spage | 1174 | en_HK |
dc.identifier.epage | 1178 | en_HK |
dc.identifier.isi | WOS:000290206600028 | - |
dc.publisher.place | Germany | en_HK |
dc.identifier.scopusauthorid | Chen, GQ=37100986900 | en_HK |
dc.identifier.scopusauthorid | Xu, ZJ=8708548900 | en_HK |
dc.identifier.scopusauthorid | Liu, Y=8225912600 | en_HK |
dc.identifier.scopusauthorid | Zhou, CY=35742480200 | en_HK |
dc.identifier.scopusauthorid | Che, CM=7102442791 | en_HK |
dc.identifier.issnl | 0936-5214 | - |