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Conference Paper: Metal-ligand multiple bonds. Oxo, imido and nitrido complexes of ruthenium and osmium

TitleMetal-ligand multiple bonds. Oxo, imido and nitrido complexes of ruthenium and osmium
Authors
Che, CM
KeywordsChemistry engineering
Chemical engineering
Issue Date1995
PublisherInternational Union of Pure and Applied Chemistry. The Journal's web site is located at http://www.degruyter.com/view/j/pac
Citation
The 30th International Conference on Coordination Chemistry, Kyoto, Japan, 24-29 July 1994. In Pure and Applied Chemistry, 1995, v. 67 n. 2, p. 225-232 How to Cite?
DOI: http://dx.doi.org/10.1351/pac199567020225
AbstractRu=O complexes have been demonstrated to be competent oxidants for oxidation of saturated hydrocarbons and epoxidation of alkenes . Photoexcitation of transdioxoosmium( V1) gives rise to super-oxidizing complexes having EO >2.2 V vs. n.h.e.. Some cationic RuZN and OsZN complexes are good model system for study of the mechanism of metalcatalysed oxidation of ammonia to nitrite and activation of diiiitrogen molecule. With 2,3-diamino-2,3-dimethylbutane as ligand, reversible Os(1V)-amide/Os(III)-amine and Ru(V)- imido/Ru(II)-amine redox couplexes are observed.
Persistent Identifierhttp://hdl.handle.net/10722/45693
ISSN
0033-4545
2023 Impact Factor: 2.0
2023 SCImago Journal Rankings: 0.435
ISI Accession Number ID
WOS:A1995QG30800003

 

DC FieldValueLanguage
dc.contributor.authorChe, CM-
dc.date.accessioned2007-10-30T06:32:52Z-
dc.date.available2007-10-30T06:32:52Z-
dc.date.issued1995-
dc.identifier.citationThe 30th International Conference on Coordination Chemistry, Kyoto, Japan, 24-29 July 1994. In Pure and Applied Chemistry, 1995, v. 67 n. 2, p. 225-232-
dc.identifier.issn0033-4545-
dc.identifier.urihttp://hdl.handle.net/10722/45693-
dc.description.abstractRu=O complexes have been demonstrated to be competent oxidants for oxidation of saturated hydrocarbons and epoxidation of alkenes . Photoexcitation of transdioxoosmium( V1) gives rise to super-oxidizing complexes having EO >2.2 V vs. n.h.e.. Some cationic RuZN and OsZN complexes are good model system for study of the mechanism of metalcatalysed oxidation of ammonia to nitrite and activation of diiiitrogen molecule. With 2,3-diamino-2,3-dimethylbutane as ligand, reversible Os(1V)-amide/Os(III)-amine and Ru(V)- imido/Ru(II)-amine redox couplexes are observed.-
dc.format.extent531535 bytes-
dc.format.extent4079 bytes-
dc.format.mimetypeapplication/pdf-
dc.format.mimetypetext/plain-
dc.languageeng-
dc.publisherInternational Union of Pure and Applied Chemistry. The Journal's web site is located at http://www.degruyter.com/view/j/pac-
dc.relation.ispartofPure and Applied Chemistry-
dc.rights© 1995 IUPAC. The final publication is available at www.degruyter.com-
dc.subjectChemistry engineering-
dc.subjectChemical engineering-
dc.titleMetal-ligand multiple bonds. Oxo, imido and nitrido complexes of ruthenium and osmium-
dc.typeConference_Paper-
dc.identifier.emailChe, CM: cmche@hku.hk-
dc.description.naturepublished_or_final_version-
dc.identifier.doi10.1351/pac199567020225-
dc.identifier.scopuseid_2-s2.0-0001510851-
dc.identifier.hkuros1433-
dc.identifier.volume67-
dc.identifier.issue2-
dc.identifier.spage225-
dc.identifier.epage232-
dc.identifier.isiWOS:A1995QG30800003-
dc.publisher.placeUnited States-
dc.identifier.issnl0033-4545-

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