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Conference Paper: Dinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling

TitleDinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling
Authors
Issue Date2013
Citation
Australian Journal of Chemistry, 2013, v. 66, n. 9, p. 1029-1033 How to Cite?
AbstractA new dinuclear Cu(ii) complex [Cu2Cl4(L1) 2] (1) (L1≤1-(2-picolyl)-4-hexyl-1H-1,2,3-triazole) has been synthesised and characterised by single-crystal X-ray diffraction (XRD) and powder XRD, thermogravimetric analysis, electron paramagnetic resonance spectrum, photoluminescence, and magnetic measurements. Complex 1 shows double 1,2,3-triazoles bridging the dinuclear Cu2N4 moiety, in which the bridging N≤N bond indicates basal-apical asymmetric mode with 112.6° torsion angle of Cu-N≤N-Cu. Different from most azole-bridged dinuclear Cu(ii) with antiferromagnetic couplings, complex 1 shows an intramolecular weak ferromagnetic interaction (J≤0.91cm-1). © 2013 CSIRO.
Persistent Identifierhttp://hdl.handle.net/10722/219714
ISSN
2015 Impact Factor: 1.427
2015 SCImago Journal Rankings: 0.548

 

DC FieldValueLanguage
dc.contributor.authorBai, Shi Qiang-
dc.contributor.authorJiang, Lu-
dc.contributor.authorZuo, Jing Lin-
dc.contributor.authorYan, Chun Hua-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:47Z-
dc.date.available2015-09-23T02:57:47Z-
dc.date.issued2013-
dc.identifier.citationAustralian Journal of Chemistry, 2013, v. 66, n. 9, p. 1029-1033-
dc.identifier.issn0004-9425-
dc.identifier.urihttp://hdl.handle.net/10722/219714-
dc.description.abstractA new dinuclear Cu(ii) complex [Cu2Cl4(L1) 2] (1) (L1≤1-(2-picolyl)-4-hexyl-1H-1,2,3-triazole) has been synthesised and characterised by single-crystal X-ray diffraction (XRD) and powder XRD, thermogravimetric analysis, electron paramagnetic resonance spectrum, photoluminescence, and magnetic measurements. Complex 1 shows double 1,2,3-triazoles bridging the dinuclear Cu2N4 moiety, in which the bridging N≤N bond indicates basal-apical asymmetric mode with 112.6° torsion angle of Cu-N≤N-Cu. Different from most azole-bridged dinuclear Cu(ii) with antiferromagnetic couplings, complex 1 shows an intramolecular weak ferromagnetic interaction (J≤0.91cm-1). © 2013 CSIRO.-
dc.languageeng-
dc.relation.ispartofAustralian Journal of Chemistry-
dc.titleDinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling-
dc.typeConference_Paper-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1071/CH13224-
dc.identifier.scopuseid_2-s2.0-84884177497-
dc.identifier.volume66-
dc.identifier.issue9-
dc.identifier.spage1029-
dc.identifier.epage1033-
dc.identifier.eissn1445-0038-

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