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Conference Paper: A comparative study on metal-metal interaction in binuclear two- and three-coordinated d10-metal complexes: Spectroscopic investigation of M(I)-M(I) interaction in the 1[dσ*pσ] excited state of [M2(dcpm)2]2+ (dcpm = bis(dicyclohexylphosphino)methane) (M = Au, Ag, Cu) and [M2(dmpm) 3]2+

TitleA comparative study on metal-metal interaction in binuclear two- and three-coordinated d10-metal complexes: Spectroscopic investigation of M(I)-M(I) interaction in the 1[dσ*pσ] excited state of [M2(dcpm)2]2+ (dcpm = bis(dicyclohexylphosphino)methane) (M = Au, Ag, Cu) and [M2(dmpm) 3]2+
Authors
KeywordsAurophilicity
Copper
Metal-Metal Interactions
Raman Spectroscopy
Silver
Issue Date2005
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccr
Citation
Coordination Chemistry Reviews, 2005, v. 249 n. 13-14, p. 1476-1490 How to Cite?
AbstractAn overview of an UV-vis spectroscopic and resonance Raman investigation of the lowest energy dipole-allowed absorption band of [M2(dcpm) 2]2+ (M = Au, Ag, Cu) and [M2(dmpm) 3]2+ (M = Au, Ag, Cu) complexes is presented. The UV-vis absorption spectra of [M2(dcpm)2]2+ and [M 2(dmpm)3]2+ feature intense low energy ndσ* → (n + 1)pσ transition with transition energy increase from two- to three-coordinated complexes and for [M2(dcpm) 2]2+ falls in the order: Ag > Au > Cu. A resonance Raman intensity analysis of the spectra allows estimation of the structural changes of the 1[dσ*pσ] excited states relative to the ground state. The structural changes in these compounds are compared with each other and with other related compounds. The metal-metal bonds are found to be very similar for the ground and excited states of the [Au2(dcpm) 2]2+ and [Au2(dmpm)3]2+ complexes but significantly different for the [Cu2(dcpm) 2]2+ and [Cu2(dmpm)3]2+ complexes that have weaker metal-metal bonding. © 2004 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/168819
ISSN
2015 Impact Factor: 12.994
2015 SCImago Journal Rankings: 4.100
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorPhillips, DLen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorKing, HLen_US
dc.contributor.authorMao, Zen_US
dc.contributor.authorTse, MCen_US
dc.date.accessioned2012-10-08T03:34:36Z-
dc.date.available2012-10-08T03:34:36Z-
dc.date.issued2005en_US
dc.identifier.citationCoordination Chemistry Reviews, 2005, v. 249 n. 13-14, p. 1476-1490en_US
dc.identifier.issn0010-8545en_US
dc.identifier.urihttp://hdl.handle.net/10722/168819-
dc.description.abstractAn overview of an UV-vis spectroscopic and resonance Raman investigation of the lowest energy dipole-allowed absorption band of [M2(dcpm) 2]2+ (M = Au, Ag, Cu) and [M2(dmpm) 3]2+ (M = Au, Ag, Cu) complexes is presented. The UV-vis absorption spectra of [M2(dcpm)2]2+ and [M 2(dmpm)3]2+ feature intense low energy ndσ* → (n + 1)pσ transition with transition energy increase from two- to three-coordinated complexes and for [M2(dcpm) 2]2+ falls in the order: Ag > Au > Cu. A resonance Raman intensity analysis of the spectra allows estimation of the structural changes of the 1[dσ*pσ] excited states relative to the ground state. The structural changes in these compounds are compared with each other and with other related compounds. The metal-metal bonds are found to be very similar for the ground and excited states of the [Au2(dcpm) 2]2+ and [Au2(dmpm)3]2+ complexes but significantly different for the [Cu2(dcpm) 2]2+ and [Cu2(dmpm)3]2+ complexes that have weaker metal-metal bonding. © 2004 Elsevier B.V. All rights reserved.en_US
dc.languageengen_US
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ccren_US
dc.relation.ispartofCoordination Chemistry Reviewsen_US
dc.rightsCoordination Chemistry Reviews. Copyright © Elsevier BV.-
dc.subjectAurophilicityen_US
dc.subjectCopperen_US
dc.subjectMetal-Metal Interactionsen_US
dc.subjectRaman Spectroscopyen_US
dc.subjectSilveren_US
dc.titleA comparative study on metal-metal interaction in binuclear two- and three-coordinated d10-metal complexes: Spectroscopic investigation of M(I)-M(I) interaction in the 1[dσ*pσ] excited state of [M2(dcpm)2]2+ (dcpm = bis(dicyclohexylphosphino)methane) (M = Au, Ag, Cu) and [M2(dmpm) 3]2+en_US
dc.typeConference_Paperen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1016/j.ccr.2004.09.015en_US
dc.identifier.scopuseid_2-s2.0-23144442045en_US
dc.identifier.hkuros111875-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-23144442045&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume249en_US
dc.identifier.issue13-14en_US
dc.identifier.spage1476en_US
dc.identifier.epage1490en_US
dc.identifier.isiWOS:000231398600018-
dc.publisher.placeNetherlandsen_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridKing, HL=8534235500en_US
dc.identifier.scopusauthoridMao, Z=7202633924en_US
dc.identifier.scopusauthoridTse, MC=7103352654en_US

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