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Article: {XW12O40 [Cu(en)2(H2O)]3} (X=V, Si): Two novel tri-supported Keggin POMs with transition metal complexes

Title{XW12O40 [Cu(en)2(H2O)]3} (X=V, Si): Two novel tri-supported Keggin POMs with transition metal complexes
Authors
KeywordsMagnetism
Polyoxometalates
Supramolecular
Transition Metal Complex
Tri-Supported
Issue Date2009
PublisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/jssc
Citation
Journal of Solid State Chemistry, 2009, v. 182 n. 8, p. 2111-2117 How to Cite?
AbstractTwo novel polyoxometalate derivatives, {XIVWVI 10WV 2O40[Cu(en)2(H2O)]3} [X=V (1), Si (2); en=ethylenediamine], have been hydrothermally synthesized and characterized by elemental analyses, IR, UV-Vis, XPS, EPR, TG and single crystal X-ray diffraction analyses. They represent the first classical Keggin polyoxoanion supported by three transition metal complex moieties, which further act as the neutral molecular unit for the construction of the interesting three-dimensional supramolecular frameworks. The magnetic properties of 1 have also been studied in the temperature range of 4-300 K, and its magnetic susceptibility obeys the Curie-Weiss law, showing antiferromagnetic coupling. © 2009 Elsevier Inc. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/92211
ISSN
2015 Impact Factor: 2.265
2015 SCImago Journal Rankings: 0.703
ISI Accession Number ID
Funding AgencyGrant Number
National Natural Science Foundation of China20571021
Funding Information:

This work was supported by the National Natural Science Foundation of China (no. 20571021).

References

 

DC FieldValueLanguage
dc.contributor.authorLu, Y-Ken_HK
dc.contributor.authorCui, X-Ben_HK
dc.contributor.authorChen, Yen_HK
dc.contributor.authorXu, J-Nen_HK
dc.contributor.authorZhang, Q-Ben_HK
dc.contributor.authorLiu, Y-Ben_HK
dc.contributor.authorXu, J-Qen_HK
dc.contributor.authorWang, T-Gen_HK
dc.date.accessioned2010-09-17T10:39:21Z-
dc.date.available2010-09-17T10:39:21Z-
dc.date.issued2009en_HK
dc.identifier.citationJournal of Solid State Chemistry, 2009, v. 182 n. 8, p. 2111-2117en_HK
dc.identifier.issn0022-4596en_HK
dc.identifier.urihttp://hdl.handle.net/10722/92211-
dc.description.abstractTwo novel polyoxometalate derivatives, {XIVWVI 10WV 2O40[Cu(en)2(H2O)]3} [X=V (1), Si (2); en=ethylenediamine], have been hydrothermally synthesized and characterized by elemental analyses, IR, UV-Vis, XPS, EPR, TG and single crystal X-ray diffraction analyses. They represent the first classical Keggin polyoxoanion supported by three transition metal complex moieties, which further act as the neutral molecular unit for the construction of the interesting three-dimensional supramolecular frameworks. The magnetic properties of 1 have also been studied in the temperature range of 4-300 K, and its magnetic susceptibility obeys the Curie-Weiss law, showing antiferromagnetic coupling. © 2009 Elsevier Inc. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/jsscen_HK
dc.relation.ispartofJournal of Solid State Chemistryen_HK
dc.subjectMagnetismen_HK
dc.subjectPolyoxometalatesen_HK
dc.subjectSupramolecularen_HK
dc.subjectTransition Metal Complexen_HK
dc.subjectTri-Supporteden_HK
dc.title{XW12O40 [Cu(en)2(H2O)]3} (X=V, Si): Two novel tri-supported Keggin POMs with transition metal complexesen_HK
dc.typeArticleen_HK
dc.identifier.emailChen, Y:ychenc@hkucc.hku.hken_HK
dc.identifier.authorityChen, Y=rp1318en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jssc.2009.05.030en_HK
dc.identifier.scopuseid_2-s2.0-68049115473en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-68049115473&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume182en_HK
dc.identifier.issue8en_HK
dc.identifier.spage2111en_HK
dc.identifier.epage2117en_HK
dc.identifier.eissn1095-726X-
dc.identifier.isiWOS:000269066400018-
dc.identifier.citeulike5073006-

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