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Article: Two supramolecular compounds based on cage-like polyoxovanadates: Syntheses, crystal structures, and characterizations

TitleTwo supramolecular compounds based on cage-like polyoxovanadates: Syntheses, crystal structures, and characterizations
Authors
KeywordsCrystal Structure
Hydrogen Bonds
Hydrothermal Synthesis
Polyoxovanadates
Supramolecular Framework
Issue Date2009
PublisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00958972.asp
Citation
Journal of Coordination Chemistry, 2009, v. 62 n. 18, p. 2937-2948 How to Cite?
AbstractTwo supramolecular compounds [Fe(2,2′-bipy)3]2[V7 VV9 IVO38(Cl)]·4.67H2O (1) and [Ni(enMe)3]2[H4V5 VV10 IVO36(Cl)] 2H2O (2) have been prepared under hydrothermal conditions and characterized by elemental analyses, IR, TGA, ESR, magnetic properties, and single crystal X-ray diffraction analyses. Crystal data for 1: tetragonal, I-42d, a=13.6043(19), b=13.6043(19), c=50.544(10)A°, V=9354(3)A°3; for 2: hexagonal, P6(3)/m, a=12.6046(12), b=12.6046(12), c=22.563(5)A°, V=3104.4(7)A°3. Compound 1 is constructed from cations [Fe(2,2′-bipy)3]3+, polyoxovanadates [V7 VV9 IVO38(Cl)]8-, and water molecules. Compound 2 is composed of cations [Ni(enMe)3]2+, clusters [H4V5 VV10 IVO36(Cl)]8-, and water molecules. There are hydrogen-bonding interactions between polyoxovanadates, organic moieties, and/or water molecules in 1 and 2, forming different 2-D layered networks. © 2009 Taylor & Francis.
Persistent Identifierhttp://hdl.handle.net/10722/92053
ISSN
2015 Impact Factor: 1.756
2015 SCImago Journal Rankings: 0.404
ISI Accession Number ID
Funding AgencyGrant Number
National Natural Science Foundation of China20333070
20571032
Funding Information:

This work was supported by the National Natural Science Foundation of China (Nos 20333070 and 20571032).

References

 

DC FieldValueLanguage
dc.contributor.authorShi, S-Yen_HK
dc.contributor.authorChen, Yen_HK
dc.contributor.authorLiu, Ben_HK
dc.contributor.authorLu, Y-Ken_HK
dc.contributor.authorXu, J-Nen_HK
dc.contributor.authorCui, X-Ben_HK
dc.contributor.authorXu, J-Qen_HK
dc.date.accessioned2010-09-17T10:34:42Z-
dc.date.available2010-09-17T10:34:42Z-
dc.date.issued2009en_HK
dc.identifier.citationJournal of Coordination Chemistry, 2009, v. 62 n. 18, p. 2937-2948en_HK
dc.identifier.issn0095-8972en_HK
dc.identifier.urihttp://hdl.handle.net/10722/92053-
dc.description.abstractTwo supramolecular compounds [Fe(2,2′-bipy)3]2[V7 VV9 IVO38(Cl)]·4.67H2O (1) and [Ni(enMe)3]2[H4V5 VV10 IVO36(Cl)] 2H2O (2) have been prepared under hydrothermal conditions and characterized by elemental analyses, IR, TGA, ESR, magnetic properties, and single crystal X-ray diffraction analyses. Crystal data for 1: tetragonal, I-42d, a=13.6043(19), b=13.6043(19), c=50.544(10)A°, V=9354(3)A°3; for 2: hexagonal, P6(3)/m, a=12.6046(12), b=12.6046(12), c=22.563(5)A°, V=3104.4(7)A°3. Compound 1 is constructed from cations [Fe(2,2′-bipy)3]3+, polyoxovanadates [V7 VV9 IVO38(Cl)]8-, and water molecules. Compound 2 is composed of cations [Ni(enMe)3]2+, clusters [H4V5 VV10 IVO36(Cl)]8-, and water molecules. There are hydrogen-bonding interactions between polyoxovanadates, organic moieties, and/or water molecules in 1 and 2, forming different 2-D layered networks. © 2009 Taylor & Francis.en_HK
dc.languageengen_HK
dc.publisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00958972.aspen_HK
dc.relation.ispartofJournal of Coordination Chemistryen_HK
dc.subjectCrystal Structureen_HK
dc.subjectHydrogen Bondsen_HK
dc.subjectHydrothermal Synthesisen_HK
dc.subjectPolyoxovanadatesen_HK
dc.subjectSupramolecular Frameworken_HK
dc.titleTwo supramolecular compounds based on cage-like polyoxovanadates: Syntheses, crystal structures, and characterizationsen_HK
dc.typeArticleen_HK
dc.identifier.emailChen, Y:ychenc@hkucc.hku.hken_HK
dc.identifier.authorityChen, Y=rp1318en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1080/00958970902962238en_HK
dc.identifier.scopuseid_2-s2.0-69949096625en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-69949096625&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume62en_HK
dc.identifier.issue18en_HK
dc.identifier.spage2937en_HK
dc.identifier.epage2948en_HK
dc.identifier.eissn1029-0389-
dc.identifier.isiWOS:000268704700002-

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