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Article: Near-infrared laser spectroscopy of TiS: The b1II-X3Δ transition

TitleNear-infrared laser spectroscopy of TiS: The b1II-X3Δ transition
Authors
Issue Date2000
PublisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmsp
Citation
Journal Of Molecular Spectroscopy, 2000, v. 203 n. 1, p. 96-104 How to Cite?
AbstractLaser-induced fluorescence spectrum of TiS in the 769-863 nm region has been recorded and analyzed. The TiS molecule was produced using the technique of laser vaporization/reaction with supersonic cooling. Twenty-one weak subbands have been assigned as being due to b 1II-X 3, B 3II 0-X 3Δ 1, and C 3Δ-X 3Δ transitions. Strong evidence shows that the b 1II state is responsible for perturbing the v = 0, 1, and 2 levels of the C 3Δ 1 subband. The molecular constants of the b 1II state have been determined as follows: T e = 10 589.47 cm -1, ω e = 542.14 cm -1, ω ex e = 3.16 cm -1, B e = 0.19568 cm -1, and α e = 0.00085 cm -1. The spin-orbit interaction between the b 1II (v = 2 and 3) and C 3Δ (v = 1 and 2) levels is discussed in terms of configuration interaction occurring between the b 1II from the 11σ 1 5π 1 configuration and the 1II from the 5π 1 1δ 1 configuration, and the C 3Δ state from 12σ 1 1δ 1 configuration, © 2000 Academic Press.
Persistent Identifierhttp://hdl.handle.net/10722/91727
ISSN
2015 Impact Factor: 1.593
2015 SCImago Journal Rankings: 0.543
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorCheung, ASCen_HK
dc.contributor.authorRan, Qen_HK
dc.contributor.authorTam, WSen_HK
dc.contributor.authorMok, DKWen_HK
dc.contributor.authorYeung, PMen_HK
dc.date.accessioned2010-09-17T10:24:33Z-
dc.date.available2010-09-17T10:24:33Z-
dc.date.issued2000en_HK
dc.identifier.citationJournal Of Molecular Spectroscopy, 2000, v. 203 n. 1, p. 96-104en_HK
dc.identifier.issn0022-2852en_HK
dc.identifier.urihttp://hdl.handle.net/10722/91727-
dc.description.abstractLaser-induced fluorescence spectrum of TiS in the 769-863 nm region has been recorded and analyzed. The TiS molecule was produced using the technique of laser vaporization/reaction with supersonic cooling. Twenty-one weak subbands have been assigned as being due to b 1II-X 3, B 3II 0-X 3Δ 1, and C 3Δ-X 3Δ transitions. Strong evidence shows that the b 1II state is responsible for perturbing the v = 0, 1, and 2 levels of the C 3Δ 1 subband. The molecular constants of the b 1II state have been determined as follows: T e = 10 589.47 cm -1, ω e = 542.14 cm -1, ω ex e = 3.16 cm -1, B e = 0.19568 cm -1, and α e = 0.00085 cm -1. The spin-orbit interaction between the b 1II (v = 2 and 3) and C 3Δ (v = 1 and 2) levels is discussed in terms of configuration interaction occurring between the b 1II from the 11σ 1 5π 1 configuration and the 1II from the 5π 1 1δ 1 configuration, and the C 3Δ state from 12σ 1 1δ 1 configuration, © 2000 Academic Press.en_HK
dc.languageengen_HK
dc.publisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/yjmspen_HK
dc.relation.ispartofJournal of Molecular Spectroscopyen_HK
dc.titleNear-infrared laser spectroscopy of TiS: The b1II-X3Δ transitionen_HK
dc.typeArticleen_HK
dc.identifier.emailCheung, ASC:hrsccsc@hku.hken_HK
dc.identifier.emailYeung, PM:pmlyeung@hku.hken_HK
dc.identifier.authorityCheung, ASC=rp00676en_HK
dc.identifier.authorityYeung, PM=rp01402en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1006/jmsp.2000.8161en_HK
dc.identifier.scopuseid_2-s2.0-0034275424en_HK
dc.identifier.hkuros58804-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0034275424&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume203en_HK
dc.identifier.issue1en_HK
dc.identifier.spage96en_HK
dc.identifier.epage104en_HK
dc.identifier.isiWOS:000088952200011-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridCheung, ASC=7401806538en_HK
dc.identifier.scopusauthoridRan, Q=7007145640en_HK
dc.identifier.scopusauthoridTam, WS=7102605536en_HK
dc.identifier.scopusauthoridMok, DKW=7005683712en_HK
dc.identifier.scopusauthoridYeung, PM=8350940900en_HK

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