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Article: Periodical variation of electronic properties in polyhydroxylated metallofullerene materials

TitlePeriodical variation of electronic properties in polyhydroxylated metallofullerene materials
Authors
KeywordsAbsorption Spectroscopy
Electronic Properties
Hydroxylation
Purification
Synthesis (Chemical)
X Ray Spectroscopy
Issue Date2006
PublisherWiley - V C H Verlag GmbH & Co KGaA
Citation
Advanced Materials, 2006, v. 18 n. 11, p. 1458-1462 How to Cite?
AbstractPolyhydroxylation of metallofullerenes to control the electronic properties of the material was investigated. The Gd@C82 and Gd@C 82(OH)x materials with a changing number of hydroxyls were purified and synthesized. The electronic properties of the Gd@C 82(OH)x film using synchrotron radiation photoemission spectroscopy (SRPES) and X-ray absorption spectroscopy (SRXAS) were studied. It was observed that when the OH groups reach a certain number in Gd@C 82(OH)x, the electron emission of the innermost Gd shows a periodical emergence or disappearance, depending on the addition of the number of hydroxyls on to the outer surface of the fullerene cages. The results suggested polyhydroxylation of metallofullerene to be a new way for designing materials with novel electronic, optical, or magnetic functions.
Persistent Identifierhttp://hdl.handle.net/10722/91265
ISSN
2015 Impact Factor: 18.96
2015 SCImago Journal Rankings: 9.021
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorTang, Jen_HK
dc.contributor.authorXing, Gen_HK
dc.contributor.authorZhao, Yen_HK
dc.contributor.authorJing, Len_HK
dc.contributor.authorGao, Xen_HK
dc.contributor.authorCheng, Yen_HK
dc.contributor.authorYuan, Hen_HK
dc.contributor.authorZhao, Fen_HK
dc.contributor.authorChen, Zen_HK
dc.contributor.authorMeng, Hen_HK
dc.contributor.authorZhang, Hen_HK
dc.contributor.authorQian, Hen_HK
dc.contributor.authorSu, Ren_HK
dc.contributor.authorIbrahim, Ken_HK
dc.date.accessioned2010-09-17T10:15:53Z-
dc.date.available2010-09-17T10:15:53Z-
dc.date.issued2006en_HK
dc.identifier.citationAdvanced Materials, 2006, v. 18 n. 11, p. 1458-1462en_HK
dc.identifier.issn0935-9648en_HK
dc.identifier.urihttp://hdl.handle.net/10722/91265-
dc.description.abstractPolyhydroxylation of metallofullerenes to control the electronic properties of the material was investigated. The Gd@C82 and Gd@C 82(OH)x materials with a changing number of hydroxyls were purified and synthesized. The electronic properties of the Gd@C 82(OH)x film using synchrotron radiation photoemission spectroscopy (SRPES) and X-ray absorption spectroscopy (SRXAS) were studied. It was observed that when the OH groups reach a certain number in Gd@C 82(OH)x, the electron emission of the innermost Gd shows a periodical emergence or disappearance, depending on the addition of the number of hydroxyls on to the outer surface of the fullerene cages. The results suggested polyhydroxylation of metallofullerene to be a new way for designing materials with novel electronic, optical, or magnetic functions.en_HK
dc.languageengen_HK
dc.publisherWiley - V C H Verlag GmbH & Co KGaAen_HK
dc.relation.ispartofAdvanced Materialsen_HK
dc.subjectAbsorption Spectroscopyen_HK
dc.subjectElectronic Propertiesen_HK
dc.subjectHydroxylationen_HK
dc.subjectPurificationen_HK
dc.subjectSynthesis (Chemical)en_HK
dc.subjectX Ray Spectroscopyen_HK
dc.titlePeriodical variation of electronic properties in polyhydroxylated metallofullerene materialsen_HK
dc.typeArticleen_HK
dc.identifier.emailCheng, Y:yuecheng@hku.hken_HK
dc.identifier.authorityCheng, Y=rp1320en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/adma.200600049en_HK
dc.identifier.scopuseid_2-s2.0-33745166633en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33745166633&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume18en_HK
dc.identifier.issue11en_HK
dc.identifier.spage1458en_HK
dc.identifier.epage1462en_HK
dc.identifier.isiWOS:000238203300023-

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