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Article: Synthesis and characterization of solid-phase graft copolymer of polypropylene with styrene and maleic anhydride
Title | Synthesis and characterization of solid-phase graft copolymer of polypropylene with styrene and maleic anhydride |
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Authors | |
Issue Date | 2000 |
Publisher | John Wiley & Sons, Inc. The Journal's web site is located at http://www.interscience.wiley.com/jpages/0021-8995/ |
Citation | Journal Of Applied Polymer Science, 2000, v. 78 n. 14, p. 2482-2487 How to Cite? |
Abstract | Polypropylene (PP) was modified by solid-phase graft copolymerization with maleic anhydride (MAH) and styrene (St), using benzoyl peroxide as the initiator and xylene as the interfacial agent. Effects of various factors such as monomer concentration, monomer ratio, initiator concentration on grafting percentage, and acid value were investigated. The graft copolymer was characterized by Fourier transform infrared, pyrolysis gas chromatography - mass spectroscopy, and dynamic mechanical analysis, and the intrinsic viscosity of the extractive from the reaction product was investigated. The results showed that the grafting percentage and acid value of the graft copolymer of PP with two monomers (MAH and St) were considerably higher than those of the graft copolymer of PP with MAH alone. The graft segments were shown to be the copolymer of St and MAH with a substantial molecular weight. |
Persistent Identifier | http://hdl.handle.net/10722/76050 |
ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.557 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Jia, D | en_HK |
dc.contributor.author | Luo, Y | en_HK |
dc.contributor.author | Li, Y | en_HK |
dc.contributor.author | Lu, H | en_HK |
dc.contributor.author | Fu, W | en_HK |
dc.contributor.author | Cheung, WL | en_HK |
dc.date.accessioned | 2010-09-06T07:17:08Z | - |
dc.date.available | 2010-09-06T07:17:08Z | - |
dc.date.issued | 2000 | en_HK |
dc.identifier.citation | Journal Of Applied Polymer Science, 2000, v. 78 n. 14, p. 2482-2487 | en_HK |
dc.identifier.issn | 0021-8995 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/76050 | - |
dc.description.abstract | Polypropylene (PP) was modified by solid-phase graft copolymerization with maleic anhydride (MAH) and styrene (St), using benzoyl peroxide as the initiator and xylene as the interfacial agent. Effects of various factors such as monomer concentration, monomer ratio, initiator concentration on grafting percentage, and acid value were investigated. The graft copolymer was characterized by Fourier transform infrared, pyrolysis gas chromatography - mass spectroscopy, and dynamic mechanical analysis, and the intrinsic viscosity of the extractive from the reaction product was investigated. The results showed that the grafting percentage and acid value of the graft copolymer of PP with two monomers (MAH and St) were considerably higher than those of the graft copolymer of PP with MAH alone. The graft segments were shown to be the copolymer of St and MAH with a substantial molecular weight. | en_HK |
dc.language | eng | en_HK |
dc.publisher | John Wiley & Sons, Inc. The Journal's web site is located at http://www.interscience.wiley.com/jpages/0021-8995/ | en_HK |
dc.relation.ispartof | Journal of Applied Polymer Science | en_HK |
dc.rights | Journal of Applied Polymer Science. Copyright © John Wiley & Sons, Inc. | en_HK |
dc.title | Synthesis and characterization of solid-phase graft copolymer of polypropylene with styrene and maleic anhydride | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0021-8995&volume=78&spage=2482&epage=2487&date=2000&atitle=Synthesis+and+characterization+of+solid-phase+graft+copolymer+of+polypropylene+with+styrene+and+maleic+anhydride | en_HK |
dc.identifier.email | Cheung, WL:wlcheung@hkucc.hku.hk | en_HK |
dc.identifier.authority | Cheung, WL=rp00103 | en_HK |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1002/1097-4628(20001227)78:14<2482::AID-APP70>3.0.CO;2-# | en_HK |
dc.identifier.scopus | eid_2-s2.0-0034541292 | en_HK |
dc.identifier.hkuros | 59272 | en_HK |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0034541292&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 78 | en_HK |
dc.identifier.issue | 14 | en_HK |
dc.identifier.spage | 2482 | en_HK |
dc.identifier.epage | 2487 | en_HK |
dc.identifier.isi | WOS:000165099500007 | - |
dc.publisher.place | United States | en_HK |
dc.identifier.scopusauthorid | Jia, D=7101755520 | en_HK |
dc.identifier.scopusauthorid | Luo, Y=7404332512 | en_HK |
dc.identifier.scopusauthorid | Li, Y=12139233200 | en_HK |
dc.identifier.scopusauthorid | Lu, H=55186396600 | en_HK |
dc.identifier.scopusauthorid | Fu, W=7202947419 | en_HK |
dc.identifier.scopusauthorid | Cheung, WL=7202743084 | en_HK |
dc.identifier.issnl | 0021-8995 | - |