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Article: Phase-dependent conformation selection of axial and equatorial forms of iodocyclopentane

TitlePhase-dependent conformation selection of axial and equatorial forms of iodocyclopentane
Authors
Issue Date1999
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1999, v. 307 n. 5-6, p. 350-358 How to Cite?
AbstractWe have obtained Raman spectra for neat liquid iodocyclopentane and for two types of solid phases. Ab initio calculations were done to help elucidate the Raman band assignments to either the axial or equatorial conformations of iodocyclopentane. The liquid Raman spectrum displays bands for both axial and equatorial conformations of iodocyclopentane while the two solid phases exhibit a strong preference for either the axial conformation for the annealed solid phase or the equatorial conformation for the unannealed solid phase. We discuss the possible utility for using this phase-dependent conformation selection to examine the conformation dependence of solid-state photochemical reactions.
Persistent Identifierhttp://hdl.handle.net/10722/70505
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZheng, Xen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:23:30Z-
dc.date.available2010-09-06T06:23:30Z-
dc.date.issued1999en_HK
dc.identifier.citationChemical Physics Letters, 1999, v. 307 n. 5-6, p. 350-358en_HK
dc.identifier.issn0009-2614en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70505-
dc.description.abstractWe have obtained Raman spectra for neat liquid iodocyclopentane and for two types of solid phases. Ab initio calculations were done to help elucidate the Raman band assignments to either the axial or equatorial conformations of iodocyclopentane. The liquid Raman spectrum displays bands for both axial and equatorial conformations of iodocyclopentane while the two solid phases exhibit a strong preference for either the axial conformation for the annealed solid phase or the equatorial conformation for the unannealed solid phase. We discuss the possible utility for using this phase-dependent conformation selection to examine the conformation dependence of solid-state photochemical reactions.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_HK
dc.relation.ispartofChemical Physics Lettersen_HK
dc.rightsChemical Physics Letters. Copyright © Elsevier BV.en_HK
dc.titlePhase-dependent conformation selection of axial and equatorial forms of iodocyclopentaneen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0009-2614&volume=307&spage=350&epage=358&date=1999&atitle=Phase-dependent+conformation+selection+of+axial+and+equatorial+forms+of+iodocyclopentaneen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0009-2614(99)00554-0-
dc.identifier.scopuseid_2-s2.0-0347594170en_HK
dc.identifier.hkuros50356en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0347594170&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume307en_HK
dc.identifier.issue5-6en_HK
dc.identifier.spage350en_HK
dc.identifier.epage358en_HK
dc.identifier.isiWOS:000081326300011-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridZheng, X=7404090253en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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