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Article: Synthesis and characterisation of hexanuclear ruthenium clusters containing a μ4-nitrene ligand. Crystal structures of [Ru6(CO)15(μ-CO)2(μ4NH)(μ-OMe)μ3-η2-N(H)C(O)OMe] and [Ru6(CO)16(μ-CO)2(μ4-NH)(μ-OMe)(μ-NCO)]

TitleSynthesis and characterisation of hexanuclear ruthenium clusters containing a μ4-nitrene ligand. Crystal structures of [Ru6(CO)15(μ-CO)2(μ4NH)(μ-OMe)μ3-η2-N(H)C(O)OMe] and [Ru6(CO)16(μ-CO)2(μ4-NH)(μ-OMe)(μ-NCO)]
Authors
KeywordsRuthenium
Clusters
Nitrene
Carbonyl
Crystal structure
Issue Date1995
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 1995, v. 503 n. 2, p. C43-C45 How to Cite?
AbstractTwo hexaruthenium carbonyl clusters [Ru6(CO)15(μ-CO)2(μ4-NH) (μ-OMe){μ3-η2-N(H)C(O)OMe}] and [Ru6(CO)16(μ-CO)2-(μ4-NH)(μ-OMe)(μ-NCO)]2 have been isolated from the pyrolysis of H2Ru3(CO))9NOCH3, and single-crystal X-ray structure analysis shows that both 1 and 2 have a square planar arrangement of four ruthenium atoms capped by a μ4-nitrene ligand, with two additional ruthenium atoms bridging two opposite Ru-Ru edges of the square base to form a ‘boat’ form metal framework.
Persistent Identifierhttp://hdl.handle.net/10722/70488
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorLee, KKHen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:23:21Z-
dc.date.available2010-09-06T06:23:21Z-
dc.date.issued1995en_HK
dc.identifier.citationJournal of Organometallic Chemistry, 1995, v. 503 n. 2, p. C43-C45en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/70488-
dc.description.abstractTwo hexaruthenium carbonyl clusters [Ru6(CO)15(μ-CO)2(μ4-NH) (μ-OMe){μ3-η2-N(H)C(O)OMe}] and [Ru6(CO)16(μ-CO)2-(μ4-NH)(μ-OMe)(μ-NCO)]2 have been isolated from the pyrolysis of H2Ru3(CO))9NOCH3, and single-crystal X-ray structure analysis shows that both 1 and 2 have a square planar arrangement of four ruthenium atoms capped by a μ4-nitrene ligand, with two additional ruthenium atoms bridging two opposite Ru-Ru edges of the square base to form a ‘boat’ form metal framework.-
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectRuthenium-
dc.subjectClusters-
dc.subjectNitrene-
dc.subjectCarbonyl-
dc.subjectCrystal structure-
dc.titleSynthesis and characterisation of hexanuclear ruthenium clusters containing a μ4-nitrene ligand. Crystal structures of [Ru6(CO)15(μ-CO)2(μ4NH)(μ-OMe)μ3-η2-N(H)C(O)OMe] and [Ru6(CO)16(μ-CO)2(μ4-NH)(μ-OMe)(μ-NCO)]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=503&issue=1&spage=C43&epage=C45&date=1995&atitle=Synthesis+and+characterization+of+hexanuclear+ruthenium+clusters+containing+a+n4-nitrene+ligands.+Crystal+and+molecular+structures+of+[Ru6(CO)15(m-CO)2(m4-NH)(m-OMe)+{m3-h2N(H)C(O)OMe}]+and+[Ru6(CO)16(m-CO)~en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0022-328X(95)05719-6-
dc.identifier.hkuros14587en_HK
dc.identifier.volume503-
dc.identifier.issue2-
dc.identifier.spageC43-
dc.identifier.epageC45-
dc.publisher.placeSwitzerland-

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