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Article: Time-resolved resonance Raman and density functional theory investigation of the 4-biphenylnitrene dimerization reaction

TitleTime-resolved resonance Raman and density functional theory investigation of the 4-biphenylnitrene dimerization reaction
Authors
Chan, PYOng, SYBut, TYSPhillips, DL
KeywordsArylnitrenes
Azobenzene
Density functional theory
Dimerization
Issue Date2004
PublisherJohn Wiley & Sons Ltd. The Journal's web site is located at http://www3.interscience.wiley.com/cgi-bin/jhome/3420
Citation
Journal Of Raman Spectroscopy, 2004, v. 35 n. 10, p. 887-894 How to Cite?
DOI: http://dx.doi.org/10.1002/jrs.1230
AbstractThis paper reports time-resolved resonance Raman spectra for the triplet 4-biphenylnitrene and its reaction to form an azo dimer product (bis-biphenyl-4-yldiazene) in acetonitrile solution. The properties of the triplet 4-biphenylnitrenes were examined based on the results of UBPW91/cc-PVDZ computations. 4-Biphenylnitrene and its azo dimer product were also compared with results previously reported for the 4-methoxyphenylnitrene and its azo dimer product, respectively. The substitution effect of p-phenyl and p-methoxy moieties on the structure and properties of arylnitrenes and azobenzenes are briefly discussed. Copyright © 2004 John Wiley & Sons, Ltd.
Persistent Identifierhttp://hdl.handle.net/10722/70477
ISSN
0377-0486
2023 Impact Factor: 2.4
2023 SCImago Journal Rankings: 0.532
ISI Accession Number ID
WOS:000224592500012
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorChan, PYen_HK
dc.contributor.authorOng, SYen_HK
dc.contributor.authorBut, TYSen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:23:14Z-
dc.date.available2010-09-06T06:23:14Z-
dc.date.issued2004en_HK
dc.identifier.citationJournal Of Raman Spectroscopy, 2004, v. 35 n. 10, p. 887-894en_HK
dc.identifier.issn0377-0486en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70477-
dc.description.abstractThis paper reports time-resolved resonance Raman spectra for the triplet 4-biphenylnitrene and its reaction to form an azo dimer product (bis-biphenyl-4-yldiazene) in acetonitrile solution. The properties of the triplet 4-biphenylnitrenes were examined based on the results of UBPW91/cc-PVDZ computations. 4-Biphenylnitrene and its azo dimer product were also compared with results previously reported for the 4-methoxyphenylnitrene and its azo dimer product, respectively. The substitution effect of p-phenyl and p-methoxy moieties on the structure and properties of arylnitrenes and azobenzenes are briefly discussed. Copyright © 2004 John Wiley & Sons, Ltd.en_HK
dc.languageengen_HK
dc.publisherJohn Wiley & Sons Ltd. The Journal's web site is located at http://www3.interscience.wiley.com/cgi-bin/jhome/3420en_HK
dc.relation.ispartofJournal of Raman Spectroscopyen_HK
dc.rightsJournal of Raman Spectroscopy. Copyright © John Wiley & Sons Ltd.en_HK
dc.subjectArylnitrenesen_HK
dc.subjectAzobenzeneen_HK
dc.subjectDensity functional theoryen_HK
dc.subjectDimerizationen_HK
dc.titleTime-resolved resonance Raman and density functional theory investigation of the 4-biphenylnitrene dimerization reactionen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0377-0486&volume=35&spage=887&epage=894&date=2004&atitle=Time-resolved+resonance+Raman+and+density+functional+theory+investigation+of+the+4-biphenylnitrene+dimerization+reactionen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/jrs.1230en_HK
dc.identifier.scopuseid_2-s2.0-6944256524en_HK
dc.identifier.hkuros98480en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-6944256524&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume35en_HK
dc.identifier.issue10en_HK
dc.identifier.spage887en_HK
dc.identifier.epage894en_HK
dc.identifier.isiWOS:000224592500012-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridChan, PY=7403497922en_HK
dc.identifier.scopusauthoridOng, SY=7202336462en_HK
dc.identifier.scopusauthoridBut, TYS=8774303500en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK
dc.identifier.issnl0377-0486-

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