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- Publisher Website: 10.1007/BF01166175
- Scopus: eid_2-s2.0-21344463952
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Article: Oxidative addition of 2,2-dithiosalicylic acid to the cluster [Os3(CO)10(CH3CN)2]
| Title | Oxidative addition of 2,2-dithiosalicylic acid to the cluster [Os3(CO)10(CH3CN)2] |
|---|---|
| Authors | |
| Keywords | Carboxylate linkage Hydrogenation: X-ray structure analysis Triosmium clusters |
| Issue Date | 1996 |
| Publisher | Springer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1040-7278 |
| Citation | Journal of Cluster Science, 1996, v. 7, p. 37-47 How to Cite? |
| Abstract | The reaction of 2,2'-dithiosalicylic acid with two equivalents of [Os3(CO)10 (CH3CN)] in THF at −78°C yields yellow crystals of [{Os3(CO)10(μ-H)}2 (O2CC6H4S)2] 1 in moderate yield. Hydrogenetaion of 1 in refluxing CHCl3 affords [Os3(CO)1(μ-H)(O2CC6H5)] 2 in good yield. Structures of 1 and 2 have been established by single crystal X-ray structure analysis. |
| Persistent Identifier | http://hdl.handle.net/10722/70463 |
| ISSN | 2023 Impact Factor: 2.7 2023 SCImago Journal Rankings: 0.504 |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Lee, SM | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.date.accessioned | 2010-09-06T06:23:07Z | - |
| dc.date.available | 2010-09-06T06:23:07Z | - |
| dc.date.issued | 1996 | en_HK |
| dc.identifier.citation | Journal of Cluster Science, 1996, v. 7, p. 37-47 | en_HK |
| dc.identifier.issn | 1040-7278 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/70463 | - |
| dc.description.abstract | The reaction of 2,2'-dithiosalicylic acid with two equivalents of [Os3(CO)10 (CH3CN)] in THF at −78°C yields yellow crystals of [{Os3(CO)10(μ-H)}2 (O2CC6H4S)2] 1 in moderate yield. Hydrogenetaion of 1 in refluxing CHCl3 affords [Os3(CO)1(μ-H)(O2CC6H5)] 2 in good yield. Structures of 1 and 2 have been established by single crystal X-ray structure analysis. | - |
| dc.language | eng | en_HK |
| dc.publisher | Springer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1040-7278 | en_HK |
| dc.relation.ispartof | Journal of Cluster Science | en_HK |
| dc.subject | Carboxylate linkage | - |
| dc.subject | Hydrogenation: X-ray structure analysis | - |
| dc.subject | Triosmium clusters | - |
| dc.title | Oxidative addition of 2,2-dithiosalicylic acid to the cluster [Os3(CO)10(CH3CN)2] | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1040-7278&volume=7&spage=37&epage=47&date=1996&atitle=Oxidative+addition+of+2,2-dithiosalicylic+acid+to+the+cluster+[Os3(CO)10(CH3CN)2] | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.identifier.doi | 10.1007/BF01166175 | - |
| dc.identifier.scopus | eid_2-s2.0-21344463952 | - |
| dc.identifier.hkuros | 14639 | en_HK |
| dc.identifier.volume | 7 | - |
| dc.identifier.spage | 37 | - |
| dc.identifier.epage | 47 | - |
| dc.identifier.issnl | 1040-7278 | - |