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Article: Dalton communications. Synthesis of novel mixed-metal clusters of mercury and osmium; crystal and molecular structures of cis-[Os(CO)4{(µ-Hg)Os3(CO)10(µ-η2-CH=CHPh)}2] and [{Os3(CO)10(µ-η2-CH=CHPh)}2(µ4-Hg)]

TitleDalton communications. Synthesis of novel mixed-metal clusters of mercury and osmium; crystal and molecular structures of cis-[Os(CO)4{(µ-Hg)Os3(CO)10(µ-η2-CH=CHPh)}2] and [{Os3(CO)10(µ-η2-CH=CHPh)}2(µ4-Hg)]
Authors
Issue Date1995
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal of the Chemical Society Dalton Transactions, 1995, n. 8, p. 1389-1390 How to Cite?
AbstractReaction of [Os3H2(CO)10] with Hg(C≡CPh)2 afforded the novel mixed-metal clusters cis-[Os(CO)4{(μ-Hg)Os3(CO)10(μ- η2-CH=CHPh)}2] 1 and [{Os3(CO) 10(μ-η2-CH=CHPh)}2(μ4-Hg)] 2 in moderate yield, the crystal structures of which have been determined; 1 converts into 2 via Hg-Os bond cleavage under ambient conditions.
Persistent Identifierhttp://hdl.handle.net/10722/70459
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorAu, YKen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:23:05Z-
dc.date.available2010-09-06T06:23:05Z-
dc.date.issued1995en_HK
dc.identifier.citationJournal of the Chemical Society Dalton Transactions, 1995, n. 8, p. 1389-1390en_HK
dc.identifier.issn1472-7773en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70459-
dc.description.abstractReaction of [Os3H2(CO)10] with Hg(C≡CPh)2 afforded the novel mixed-metal clusters cis-[Os(CO)4{(μ-Hg)Os3(CO)10(μ- η2-CH=CHPh)}2] 1 and [{Os3(CO) 10(μ-η2-CH=CHPh)}2(μ4-Hg)] 2 in moderate yield, the crystal structures of which have been determined; 1 converts into 2 via Hg-Os bond cleavage under ambient conditions.-
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofJournal of the Chemical Society Dalton Transactionsen_HK
dc.titleDalton communications. Synthesis of novel mixed-metal clusters of mercury and osmium; crystal and molecular structures of cis-[Os(CO)4{(µ-Hg)Os3(CO)10(µ-η2-CH=CHPh)}2] and [{Os3(CO)10(µ-η2-CH=CHPh)}2(µ4-Hg)]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=8&spage=1389&epage=1390&date=1995&atitle=Synthesis+of+novel+mixed+metal+clusters+of+mercury+and+osmium;+crystal+and+molecular+structures+of+cis-[Os(CO)4+{(m-Hg)(Os3(CO)10(m-h2-C(H)=C(H)Ph)}2]+and+[(m4-Hg){Os3(CO)10(m-h2-C(H)=C(H)Ph)}2]en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1039/DT9950001389-
dc.identifier.scopuseid_2-s2.0-37049082622-
dc.identifier.hkuros1499en_HK
dc.identifier.issue8-
dc.identifier.spage1389-
dc.identifier.epage1390-
dc.identifier.isiWOS:A1995QV58700019-
dc.publisher.placeUnited Kingdom-

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