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Article: Synthesis, structure, and ion-binding studies of cobalt(II) complexes with aza-crown substituted salicylaldimine Schiff base ligand

TitleSynthesis, structure, and ion-binding studies of cobalt(II) complexes with aza-crown substituted salicylaldimine Schiff base ligand
Authors
KeywordsAza-crown
Cobalt(II) complexes
Ion-binding
Salicyladimine
Schiff base
Issue Date2003
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/ica
Citation
Inorganica Chimica Acta, 2003, v. 346, p. 49-56 How to Cite?
AbstractA series of cobalt(II) complexes with azacrown ether-containing salicylaldimine Schiff base ligand Co(L1), Co(L2)2 and Co(L3)2 has been successfully synthesized. The cation-binding properties of the complexes have been studied and the stability constants with alkali and alkaline earth metal cations determined. Synthesis of the complexes with monoaza-12-crown-4, Co(L1) and Co(L2)2, allows for a direct comparison of the cation binding properties between the mono- and bis-Schiff base systems as well as with the complex containing the monoaza-15-crown-5 pendant, i.e. Co(L3)2, which has a different crown size. The X-ray crystal structure of Co(L3)2 has also been determined. © 2002 Elsevier Science B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/70449
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLu, XXen_HK
dc.contributor.authorQin, SYen_HK
dc.contributor.authorZhou, ZYen_HK
dc.contributor.authorYam, VWWen_HK
dc.date.accessioned2010-09-06T06:22:59Z-
dc.date.available2010-09-06T06:22:59Z-
dc.date.issued2003en_HK
dc.identifier.citationInorganica Chimica Acta, 2003, v. 346, p. 49-56en_HK
dc.identifier.issn0020-1693en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70449-
dc.description.abstractA series of cobalt(II) complexes with azacrown ether-containing salicylaldimine Schiff base ligand Co(L1), Co(L2)2 and Co(L3)2 has been successfully synthesized. The cation-binding properties of the complexes have been studied and the stability constants with alkali and alkaline earth metal cations determined. Synthesis of the complexes with monoaza-12-crown-4, Co(L1) and Co(L2)2, allows for a direct comparison of the cation binding properties between the mono- and bis-Schiff base systems as well as with the complex containing the monoaza-15-crown-5 pendant, i.e. Co(L3)2, which has a different crown size. The X-ray crystal structure of Co(L3)2 has also been determined. © 2002 Elsevier Science B.V. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/icaen_HK
dc.relation.ispartofInorganica Chimica Actaen_HK
dc.rightsInorganica Chimica Acta. Copyright © Elsevier BV.en_HK
dc.subjectAza-crownen_HK
dc.subjectCobalt(II) complexesen_HK
dc.subjectIon-bindingen_HK
dc.subjectSalicyladimineen_HK
dc.subjectSchiff baseen_HK
dc.titleSynthesis, structure, and ion-binding studies of cobalt(II) complexes with aza-crown substituted salicylaldimine Schiff base liganden_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1693&volume=346&spage=49&epage=56&date=2003&atitle=Synthesis,+structure,+and+ion-binding+studies+of+cobalt(II)+complexes+with+aza-crown+substituted+salicylaldimine+Schiff+base+liganden_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0020-1693(02)01391-9en_HK
dc.identifier.scopuseid_2-s2.0-0037465642en_HK
dc.identifier.hkuros83197en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0037465642&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume346en_HK
dc.identifier.spage49en_HK
dc.identifier.epage56en_HK
dc.identifier.isiWOS:000181820600008-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridLu, XX=7404839171en_HK
dc.identifier.scopusauthoridQin, SY=7202726978en_HK
dc.identifier.scopusauthoridZhou, ZY=7406096262en_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK

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