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Article: Synthesis and structure of a novel Pd(0)-Pd(IV)-Pd(IV)-Pd(0) mixed-valence complex

TitleSynthesis and structure of a novel Pd(0)-Pd(IV)-Pd(IV)-Pd(0) mixed-valence complex
Authors
KeywordsCrystal structure
P-NMR
Palladium (II) complex
Issue Date2004
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inoche
Citation
Inorganic Chemistry Communications, 2004, v. 7 n. 6, p. 737-740 How to Cite?
AbstractThe interaction of PdCl2(PhCN)2 with 1,2-[PhP(H)CH2CH2CH2P(Ph)CH2] 2C6H4, generated in situ from the reduction of the corresponding phosphine oxide with LiAlH4 in the presence of Me3SiCl, gave a complex mixture, from which a di- and a tetra-nuclear palladium complex 1 and 2 whose solid state structures were ascertained by X-ray crystallography, were isolated. A novel Pd(0)-Pd(IV)-Pd(IV)-Pd(0) mixed-valence structure was observed in complex 2. © 2004 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/70440
ISSN
2015 Impact Factor: 1.762
2015 SCImago Journal Rankings: 0.489
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorWong, WKen_HK
dc.contributor.authorLiang, Hen_HK
dc.contributor.authorYung, MYen_HK
dc.contributor.authorGuo, JPen_HK
dc.contributor.authorYung, KFen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorEdwards, PGen_HK
dc.date.accessioned2010-09-06T06:22:54Z-
dc.date.available2010-09-06T06:22:54Z-
dc.date.issued2004en_HK
dc.identifier.citationInorganic Chemistry Communications, 2004, v. 7 n. 6, p. 737-740en_HK
dc.identifier.issn1387-7003en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70440-
dc.description.abstractThe interaction of PdCl2(PhCN)2 with 1,2-[PhP(H)CH2CH2CH2P(Ph)CH2] 2C6H4, generated in situ from the reduction of the corresponding phosphine oxide with LiAlH4 in the presence of Me3SiCl, gave a complex mixture, from which a di- and a tetra-nuclear palladium complex 1 and 2 whose solid state structures were ascertained by X-ray crystallography, were isolated. A novel Pd(0)-Pd(IV)-Pd(IV)-Pd(0) mixed-valence structure was observed in complex 2. © 2004 Elsevier B.V. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inocheen_HK
dc.relation.ispartofInorganic Chemistry Communicationsen_HK
dc.rightsInorganic Chemistry Communications. Copyright © Elsevier BV.en_HK
dc.subjectCrystal structureen_HK
dc.subjectP-NMRen_HK
dc.subjectPalladium (II) complexen_HK
dc.titleSynthesis and structure of a novel Pd(0)-Pd(IV)-Pd(IV)-Pd(0) mixed-valence complexen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1387-7003&volume=7&issue=6&spage=737&epage=740&date=2004&atitle=Synthesis+and+structure+of+a+novel+Pd(0)-Pd(IV)-Pd(IV)-Pd(0)+mixed-valence+complex+en_HK
dc.identifier.emailYung, KF: kfyung@hkucc.hku.hken_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityYung, KF=rp00837en_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.inoche.2004.04.004en_HK
dc.identifier.scopuseid_2-s2.0-2542470598en_HK
dc.identifier.hkuros91834en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-2542470598&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume7en_HK
dc.identifier.issue6en_HK
dc.identifier.spage737en_HK
dc.identifier.epage740en_HK
dc.identifier.isiWOS:000221988600008-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridWong, WK=7403972869en_HK
dc.identifier.scopusauthoridLiang, H=7402854031en_HK
dc.identifier.scopusauthoridYung, MY=7101896852en_HK
dc.identifier.scopusauthoridGuo, JP=8953662800en_HK
dc.identifier.scopusauthoridYung, KF=7006849172en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridEdwards, PG=7401881766en_HK

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