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Article: Preparation of some dinuclear rhodium complexes with the orthometallated ligand [2,6-(PPh2CH2)2C6H3] - and their catalytic activity for polymerization of phenylacetylene

TitlePreparation of some dinuclear rhodium complexes with the orthometallated ligand [2,6-(PPh2CH2)2C6H3] - and their catalytic activity for polymerization of phenylacetylene
Authors
KeywordsOrthometallation
Phosphine
Polymerization acetylene
Rhodium
Issue Date2000
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal Of Organometallic Chemistry, 2000, v. 598 n. 2, p. 228-234 How to Cite?
AbstractReaction of 1,3-(PPh2CH2)2C6H4 (PCHP) with [RhCl(COD)]2 in isopropanol produced a mixture of dinuclear complexes [RhCl(COD)]2(μ2-PCHP), RhH(PCP)(μ-Cl)2Rh(COD), and [RhHCl(PCP)]2(μ2-PCHP). Reaction of RhH(PCP)(μ-Cl)2Rh(COD) with CCl4 produced RhCl(PCP)(μ-Cl)2Rh(COD). The solid-state structure of the latter complex has been characterized by X-ray diffraction. With the exception of [RhHCl(PCP)]2(μ2-PCHP), all the dinuclear complexes in THF are catalytically active for the polymerization of phenylacetylene. © 2000 Elsevier Science S.A.
Persistent Identifierhttp://hdl.handle.net/10722/70428
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
References

 

DC FieldValueLanguage
dc.contributor.authorYao, Jen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorJia, Gen_HK
dc.date.accessioned2010-09-06T06:22:47Z-
dc.date.available2010-09-06T06:22:47Z-
dc.date.issued2000en_HK
dc.identifier.citationJournal Of Organometallic Chemistry, 2000, v. 598 n. 2, p. 228-234en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/70428-
dc.description.abstractReaction of 1,3-(PPh2CH2)2C6H4 (PCHP) with [RhCl(COD)]2 in isopropanol produced a mixture of dinuclear complexes [RhCl(COD)]2(μ2-PCHP), RhH(PCP)(μ-Cl)2Rh(COD), and [RhHCl(PCP)]2(μ2-PCHP). Reaction of RhH(PCP)(μ-Cl)2Rh(COD) with CCl4 produced RhCl(PCP)(μ-Cl)2Rh(COD). The solid-state structure of the latter complex has been characterized by X-ray diffraction. With the exception of [RhHCl(PCP)]2(μ2-PCHP), all the dinuclear complexes in THF are catalytically active for the polymerization of phenylacetylene. © 2000 Elsevier Science S.A.en_HK
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectOrthometallationen_HK
dc.subjectPhosphineen_HK
dc.subjectPolymerization acetyleneen_HK
dc.subjectRhodiumen_HK
dc.titlePreparation of some dinuclear rhodium complexes with the orthometallated ligand [2,6-(PPh2CH2)2C6H3] - and their catalytic activity for polymerization of phenylacetyleneen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=598&spage=228&epage=234&date=2000&atitle=Preparation+of+some+dinuclear+rhodium+complexes+with+the+orthometallated+ligand+[2,6-(PPh2CH2)2C6H3]-+and+their+catalytic+activity+for+polymerization+of+phenylacetyleneen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0000489579en_HK
dc.identifier.hkuros53891en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0000489579&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume598en_HK
dc.identifier.issue2en_HK
dc.identifier.spage228en_HK
dc.identifier.epage234en_HK
dc.publisher.placeSwitzerlanden_HK
dc.identifier.scopusauthoridYao, J=7403503240en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridJia, G=7103360705en_HK

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