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Article: Preparation and characterization of iron(+2) and ruthenium(+2) diiminodiphosphine complexes. X-ray crystal structures of [(η5-C5H5)Fe(immpho)][BF4] · 0.5CH2Cl2 and {[η5-C5Me5)Ru(CH3CN)]2[immpho] } {ZnCl4} · 2CH3CN · 2H2O

TitlePreparation and characterization of iron(+2) and ruthenium(+2) diiminodiphosphine complexes. X-ray crystal structures of [(η5-C5H5)Fe(immpho)][BF4] · 0.5CH2Cl2 and {[η5-C5Me5)Ru(CH3CN)]2[immpho] } {ZnCl4} · 2CH3CN · 2H2O
Authors
KeywordsRuthenium(+2)
Iron(+2)
Ruthenium(+2) dimer
Diiminodiphosphine
Cyclopentadienyl
Issue Date1996
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1996, v. 16 n. 3, p. 433-439 How to Cite?
AbstractThe interaction of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine(immpho) with one and two equivalents of [(η5-C5Me5)Ru(CH3CN)3]+ (generated in situ from the reaction of [(η5-C5Me5)RuCl2]n with excess Zn granular in CH3CN) in CH3CN at room temperature gave [(η5-C5Me5)Ru(immpho)]2 [ZnCl4] (I) and {[(η5-C5Me5)Ru(CH3CN)]2[immpho]}{ZnCl4} (II) in 80% and 7 respectively. Upon UV irradiation, immpho reacted with equal molar of [(η5C5H5)Fe(η6-mesitylene)][BF4] in CH3CN at room temperature to give [(η5-C5H5)Fe(immpho)]BF4] (III) in 41% yield. Compounds I–III have been fully characterized by analytical and spectroscopic methods. The structures of II and III have been established by X-ray diffraction.
Persistent Identifierhttp://hdl.handle.net/10722/70425
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592

 

DC FieldValueLanguage
dc.contributor.authorWong, WKen_HK
dc.contributor.authorChen, Yen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:22:45Z-
dc.date.available2010-09-06T06:22:45Z-
dc.date.issued1996en_HK
dc.identifier.citationPolyhedron, 1996, v. 16 n. 3, p. 433-439en_HK
dc.identifier.issn0277-5387en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70425-
dc.description.abstractThe interaction of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine(immpho) with one and two equivalents of [(η5-C5Me5)Ru(CH3CN)3]+ (generated in situ from the reaction of [(η5-C5Me5)RuCl2]n with excess Zn granular in CH3CN) in CH3CN at room temperature gave [(η5-C5Me5)Ru(immpho)]2 [ZnCl4] (I) and {[(η5-C5Me5)Ru(CH3CN)]2[immpho]}{ZnCl4} (II) in 80% and 7 respectively. Upon UV irradiation, immpho reacted with equal molar of [(η5C5H5)Fe(η6-mesitylene)][BF4] in CH3CN at room temperature to give [(η5-C5H5)Fe(immpho)]BF4] (III) in 41% yield. Compounds I–III have been fully characterized by analytical and spectroscopic methods. The structures of II and III have been established by X-ray diffraction.-
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_HK
dc.relation.ispartofPolyhedronen_HK
dc.rightsPolyhedron. Copyright © Elsevier BV.en_HK
dc.subjectRuthenium(+2)-
dc.subjectIron(+2)-
dc.subjectRuthenium(+2) dimer-
dc.subjectDiiminodiphosphine-
dc.subjectCyclopentadienyl-
dc.titlePreparation and characterization of iron(+2) and ruthenium(+2) diiminodiphosphine complexes. X-ray crystal structures of [(η5-C5H5)Fe(immpho)][BF4] · 0.5CH2Cl2 and {[η5-C5Me5)Ru(CH3CN)]2[immpho] } {ZnCl4} · 2CH3CN · 2H2Oen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=16&spage=433&epage=439&date=1996&atitle=Preparation+and+characterisation+of+iron(+2)+and+ruthenium(+2)+diiminodiphosphine+complexes.++X-ray+crystal+structures+of+[(h5-C5H5)Fe(immpho)][BF4]-0.5CH2Cl2+and+{[(h5-C5Me5)Ru(CH3CN)]2[immpho]}{ZnCl4}.en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0277-5387(96)00296-3-
dc.identifier.hkuros25838en_HK
dc.identifier.volume16-
dc.identifier.issue3-
dc.identifier.spage433-
dc.identifier.epage439-
dc.publisher.placeNetherlands-

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