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Article: Syntheses, photophysics, and fluxional properties of luminescent A-frame diplatinum(II) acetylide complexes

TitleSyntheses, photophysics, and fluxional properties of luminescent A-frame diplatinum(II) acetylide complexes
Authors
Issue Date1998
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallics
Citation
Organometallics, 1998, v. 17 n. 12, p. 2590-2596 How to Cite?
AbstractA series of A-frame Pt(II) acetylide complexes [Pt 2(μ-dppm) 2(μ-C≡CR)(C≡CR) 2] + (R = C 6H 5, C 6H 4OMe-P, C 6H 4OEt-P, C 6H 4Et-p, Bp, tBu) have been isolated and shown to exhibit strong luminescence in both the solid state and in fluid solution. All these A-frame acetylide complexes have been found to exhibit fluxional properties. The free energies of activation for the fluxional process of selected Pt(II) A-frame acetylide complexes have been determined.
Persistent Identifierhttp://hdl.handle.net/10722/70422
ISSN
2015 Impact Factor: 4.186
2015 SCImago Journal Rankings: 2.043
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorYeung, PKYen_HK
dc.contributor.authorChan, LPen_HK
dc.contributor.authorKwok, WMen_HK
dc.contributor.authorPhillips, DLen_HK
dc.contributor.authorYu, KLen_HK
dc.contributor.authorWong, RWKen_HK
dc.contributor.authorYan, Hen_HK
dc.contributor.authorMeng, QJen_HK
dc.date.accessioned2010-09-06T06:22:44Z-
dc.date.available2010-09-06T06:22:44Z-
dc.date.issued1998en_HK
dc.identifier.citationOrganometallics, 1998, v. 17 n. 12, p. 2590-2596en_HK
dc.identifier.issn0276-7333en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70422-
dc.description.abstractA series of A-frame Pt(II) acetylide complexes [Pt 2(μ-dppm) 2(μ-C≡CR)(C≡CR) 2] + (R = C 6H 5, C 6H 4OMe-P, C 6H 4OEt-P, C 6H 4Et-p, Bp, tBu) have been isolated and shown to exhibit strong luminescence in both the solid state and in fluid solution. All these A-frame acetylide complexes have been found to exhibit fluxional properties. The free energies of activation for the fluxional process of selected Pt(II) A-frame acetylide complexes have been determined.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/organometallicsen_HK
dc.relation.ispartofOrganometallicsen_HK
dc.titleSyntheses, photophysics, and fluxional properties of luminescent A-frame diplatinum(II) acetylide complexesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0276-7333&volume=17&spage=2590&epage=2596&date=1998&atitle=Syntheses,+photophysics,+and+fluxional+properties+of+luminescent+A-frame+diplatinum(II)+acetylide+complexesen_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/om971021d-
dc.identifier.scopuseid_2-s2.0-0000857495en_HK
dc.identifier.hkuros39855en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0000857495&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume17en_HK
dc.identifier.issue12en_HK
dc.identifier.spage2590en_HK
dc.identifier.epage2596en_HK
dc.identifier.isiWOS:000074172700030-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridYeung, PKY=7006727700en_HK
dc.identifier.scopusauthoridChan, LP=36907175200en_HK
dc.identifier.scopusauthoridKwok, WM=7103129332en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK
dc.identifier.scopusauthoridYu, KL=7403385872en_HK
dc.identifier.scopusauthoridWong, RWK=7402127088en_HK
dc.identifier.scopusauthoridYan, H=35328765400en_HK
dc.identifier.scopusauthoridMeng, QJ=7202535671en_HK

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