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Article: Metal cluster induced desulphurization of N-(p-Methoxybenzoyl)-S- Benzoyl-sulphenamide. Crystal and molecular structures of [Os6(CO)20(μ4-S)(MeCN)]

TitleMetal cluster induced desulphurization of N-(p-Methoxybenzoyl)-S- Benzoyl-sulphenamide. Crystal and molecular structures of [Os6(CO)20(μ4-S)(MeCN)]
Authors
KeywordsOsmium
Carbonyl
Cluster
Desulfurization
Crystal structure
Issue Date1995
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 1995, v. 503 n. 1, p. C19-C21 How to Cite?
AbstractReaction of N-(p-methoxybenzoyl)-S-benzoylsulphenamide1 with [Os3(CO)10(MeCN)2] at room temperature gives Os3(CO)10(μ3-S)]2 and [Os6(CO)20(μ4-S)(MeCN)]3 in moderate yield. The crystal structure of 3 has been determined. Complex 2 is an intermediate in the formation of 3. Complex 3 undergoes dissociation of CO to give [Os6(CO)19(μ3-S)] and [Os5(CO)15(μ4-S)].
Persistent Identifierhttp://hdl.handle.net/10722/70377
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLee, SMen_HK
dc.contributor.authorCheung, KKen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:22:18Z-
dc.date.available2010-09-06T06:22:18Z-
dc.date.issued1995en_HK
dc.identifier.citationJournal of Organometallic Chemistry, 1995, v. 503 n. 1, p. C19-C21en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/70377-
dc.description.abstractReaction of N-(p-methoxybenzoyl)-S-benzoylsulphenamide1 with [Os3(CO)10(MeCN)2] at room temperature gives Os3(CO)10(μ3-S)]2 and [Os6(CO)20(μ4-S)(MeCN)]3 in moderate yield. The crystal structure of 3 has been determined. Complex 2 is an intermediate in the formation of 3. Complex 3 undergoes dissociation of CO to give [Os6(CO)19(μ3-S)] and [Os5(CO)15(μ4-S)].-
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectOsmium-
dc.subjectCarbonyl-
dc.subjectCluster-
dc.subjectDesulfurization-
dc.subjectCrystal structure-
dc.titleMetal cluster induced desulphurization of N-(p-Methoxybenzoyl)-S- Benzoyl-sulphenamide. Crystal and molecular structures of [Os6(CO)20(μ4-S)(MeCN)]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=503 No1&spage=C19&epage=C21&date=1995&atitle=Metal+cluster+induced+desulphurization+of+N-(p-Methoxybenzoyl)-S-+Benzoyl-sulphenamide.+Crystal+and+molecular+structures+of+[Os6(CO)20(m4-S)(MeCN)]en_HK
dc.identifier.emailCheung, KK: kkcheung@hkucc.hku.hken_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0022-328X(95)05726-6-
dc.identifier.hkuros14595en_HK
dc.identifier.volume503-
dc.identifier.issue1-
dc.identifier.spageC19-
dc.identifier.epageC21-
dc.identifier.isiWOS:A1995TB62800025-
dc.publisher.placeSwitzerland-

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