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Article: Reaction of [N(PPh3)2][Os3(m-H)(CO)11] with [Cu(PPh3)2BH4]. Crystal and molecular structures of [Os3(m-H)(m-OH)(CO)10] and two [Os3(m-H)(m-OH)(CO)8(PPh3)2] isomeric clusters

TitleReaction of [N(PPh3)2][Os3(m-H)(CO)11] with [Cu(PPh3)2BH4]. Crystal and molecular structures of [Os3(m-H)(m-OH)(CO)10] and two [Os3(m-H)(m-OH)(CO)8(PPh3)2] isomeric clusters
Authors
Issue Date1995
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1995, v. 14 n. 20-21, p. 2849-2855 How to Cite?
AbstractReaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4] in CH2Cl2 at room temperature affords [Os3(μ-H)(μ-OH)(CO)10] (1) and two isomers 2a and 2b with a molecular formula [Os3(μ-H)(μ-OH)(CO)8(PPh3)2]. Clusters 1, 2a and 2b are all air- and moisture-stable and have been fully characterized by IR, NMR, MS and X-ray crystallography. The molecular structures of 2a and 2b are different in the substitution positions of the PPh3.
Persistent Identifierhttp://hdl.handle.net/10722/70373
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHo, WGYen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:22:15Z-
dc.date.available2010-09-06T06:22:15Z-
dc.date.issued1995en_HK
dc.identifier.citationPolyhedron, 1995, v. 14 n. 20-21, p. 2849-2855en_HK
dc.identifier.issn0277-5387en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70373-
dc.description.abstractReaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4] in CH2Cl2 at room temperature affords [Os3(μ-H)(μ-OH)(CO)10] (1) and two isomers 2a and 2b with a molecular formula [Os3(μ-H)(μ-OH)(CO)8(PPh3)2]. Clusters 1, 2a and 2b are all air- and moisture-stable and have been fully characterized by IR, NMR, MS and X-ray crystallography. The molecular structures of 2a and 2b are different in the substitution positions of the PPh3.-
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_HK
dc.relation.ispartofPolyhedronen_HK
dc.rightsPolyhedron. Copyright © Elsevier BV.en_HK
dc.titleReaction of [N(PPh3)2][Os3(m-H)(CO)11] with [Cu(PPh3)2BH4]. Crystal and molecular structures of [Os3(m-H)(m-OH)(CO)10] and two [Os3(m-H)(m-OH)(CO)8(PPh3)2] isomeric clustersen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=14&issue=2021&spage=2849&epage=2855&date=1995&atitle=Reaction+of+[N(PPh3)2][Os3(m-H)(CO)11]+with+[Cu(PPh3)2BH4].+Crystal+and+molecular+structures+of+[Os3(m-H)(m-OH)(CO)10]+and+two+[Os3(m-H)(m-OH)(CO)8(PPh3)2]+isomeric+clustersen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0277-5387(95)00208-A-
dc.identifier.hkuros14617en_HK
dc.identifier.volume14-
dc.identifier.issue20-21-
dc.identifier.spage2849-
dc.identifier.epage2855-
dc.identifier.isiWOS:A1995RW66100004-

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