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- Publisher Website: 10.1016/0277-5387(95)00208-A
- Scopus: eid_2-s2.0-0345855814
- WOS: WOS:A1995RW66100004
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Article: Reaction of [N(PPh3)2][Os3(m-H)(CO)11] with [Cu(PPh3)2BH4]. Crystal and molecular structures of [Os3(m-H)(m-OH)(CO)10] and two [Os3(m-H)(m-OH)(CO)8(PPh3)2] isomeric clusters
| Title | Reaction of [N(PPh3)2][Os3(m-H)(CO)11] with [Cu(PPh3)2BH4]. Crystal and molecular structures of [Os3(m-H)(m-OH)(CO)10] and two [Os3(m-H)(m-OH)(CO)8(PPh3)2] isomeric clusters |
|---|---|
| Authors | |
| Issue Date | 1995 |
| Publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly |
| Citation | Polyhedron, 1995, v. 14 n. 20-21, p. 2849-2855 How to Cite? |
| Abstract | Reaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4] in CH2Cl2 at room temperature affords [Os3(μ-H)(μ-OH)(CO)10] (1) and two isomers 2a and 2b with a molecular formula [Os3(μ-H)(μ-OH)(CO)8(PPh3)2]. Clusters 1, 2a and 2b are all air- and moisture-stable and have been fully characterized by IR, NMR, MS and X-ray crystallography. The molecular structures of 2a and 2b are different in the substitution positions of the PPh3. |
| Persistent Identifier | http://hdl.handle.net/10722/70373 |
| ISSN | 2023 Impact Factor: 2.4 2023 SCImago Journal Rankings: 0.379 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Ho, WGY | en_HK |
| dc.contributor.author | Wong, WT | en_HK |
| dc.date.accessioned | 2010-09-06T06:22:15Z | - |
| dc.date.available | 2010-09-06T06:22:15Z | - |
| dc.date.issued | 1995 | en_HK |
| dc.identifier.citation | Polyhedron, 1995, v. 14 n. 20-21, p. 2849-2855 | en_HK |
| dc.identifier.issn | 0277-5387 | en_HK |
| dc.identifier.uri | http://hdl.handle.net/10722/70373 | - |
| dc.description.abstract | Reaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4] in CH2Cl2 at room temperature affords [Os3(μ-H)(μ-OH)(CO)10] (1) and two isomers 2a and 2b with a molecular formula [Os3(μ-H)(μ-OH)(CO)8(PPh3)2]. Clusters 1, 2a and 2b are all air- and moisture-stable and have been fully characterized by IR, NMR, MS and X-ray crystallography. The molecular structures of 2a and 2b are different in the substitution positions of the PPh3. | - |
| dc.language | eng | en_HK |
| dc.publisher | Elsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly | en_HK |
| dc.relation.ispartof | Polyhedron | en_HK |
| dc.rights | Polyhedron. Copyright © Elsevier BV. | en_HK |
| dc.title | Reaction of [N(PPh3)2][Os3(m-H)(CO)11] with [Cu(PPh3)2BH4]. Crystal and molecular structures of [Os3(m-H)(m-OH)(CO)10] and two [Os3(m-H)(m-OH)(CO)8(PPh3)2] isomeric clusters | en_HK |
| dc.type | Article | en_HK |
| dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=14&issue=2021&spage=2849&epage=2855&date=1995&atitle=Reaction+of+[N(PPh3)2][Os3(m-H)(CO)11]+with+[Cu(PPh3)2BH4].+Crystal+and+molecular+structures+of+[Os3(m-H)(m-OH)(CO)10]+and+two+[Os3(m-H)(m-OH)(CO)8(PPh3)2]+isomeric+clusters | en_HK |
| dc.identifier.email | Wong, WT: wtwong@hku.hk | en_HK |
| dc.identifier.authority | Wong, WT=rp00811 | en_HK |
| dc.identifier.doi | 10.1016/0277-5387(95)00208-A | - |
| dc.identifier.scopus | eid_2-s2.0-0345855814 | - |
| dc.identifier.hkuros | 14617 | en_HK |
| dc.identifier.volume | 14 | - |
| dc.identifier.issue | 20-21 | - |
| dc.identifier.spage | 2849 | - |
| dc.identifier.epage | 2855 | - |
| dc.identifier.isi | WOS:A1995RW66100004 | - |
| dc.identifier.issnl | 0277-5387 | - |