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Article: Synthesis, crystal structure and catalytic activities of [RuIII(bbpc)(PPh3)Cl] [H2bbpc = 1,2-bis(4-tert-butylpyridine-2-carboxamido)-4,5-dichlorobenzene]

TitleSynthesis, crystal structure and catalytic activities of [RuIII(bbpc)(PPh3)Cl] [H2bbpc = 1,2-bis(4-tert-butylpyridine-2-carboxamido)-4,5-dichlorobenzene]
Authors
Ko, PHChen, TYZhu, JCheng, KFPeng, SMChe, CM
Issue Date1995
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1995 n. 13, p. 2215-2219 How to Cite?
DOI: http://dx.doi.org/10.1039/DT9950002215
AbstractThe compound H2bbpc [1,2-bis(4-tert-butylpyridine-2-carboxamido)-4,5-dichlorobenzene], which has good solubility in organic solvents, has been prepared. Reaction of [Ru(PPh3)3Cl2] with H2bbpc in ethanol and in the presence of triethylamine gave [RuIII(bbpc)(PPh3)Cl], the crystal structure of which has been determined. This complex is an active catalyst for alkene epoxidation by PhIO, cyclopropanation of styrene by ethyl diazoacetate and aziridination of styrene by PhINO2SC6H4Me-p. Its cyclic voltammogram in dichloromethane showed a reversible RuIII-RuII couple at -0.55 V and an oxidation couple at 0.32 V.
Persistent Identifierhttp://hdl.handle.net/10722/70364
ISSN
1472-7773
ISI Accession Number ID
WOS:A1995RJ20300015

 

DC FieldValueLanguage
dc.contributor.authorKo, PHen_HK
dc.contributor.authorChen, TYen_HK
dc.contributor.authorZhu, Jen_HK
dc.contributor.authorCheng, KFen_HK
dc.contributor.authorPeng, SMen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:22:10Z-
dc.date.available2010-09-06T06:22:10Z-
dc.date.issued1995en_HK
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1995 n. 13, p. 2215-2219en_HK
dc.identifier.issn1472-7773en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70364-
dc.description.abstractThe compound H2bbpc [1,2-bis(4-tert-butylpyridine-2-carboxamido)-4,5-dichlorobenzene], which has good solubility in organic solvents, has been prepared. Reaction of [Ru(PPh3)3Cl2] with H2bbpc in ethanol and in the presence of triethylamine gave [RuIII(bbpc)(PPh3)Cl], the crystal structure of which has been determined. This complex is an active catalyst for alkene epoxidation by PhIO, cyclopropanation of styrene by ethyl diazoacetate and aziridination of styrene by PhINO2SC6H4Me-p. Its cyclic voltammogram in dichloromethane showed a reversible RuIII-RuII couple at -0.55 V and an oxidation couple at 0.32 V.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_HK
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_HK
dc.titleSynthesis, crystal structure and catalytic activities of [RuIII(bbpc)(PPh3)Cl] [H2bbpc = 1,2-bis(4-tert-butylpyridine-2-carboxamido)-4,5-dichlorobenzene]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1472-7773&volume=&spage=2215&epage=2219&date=1995&atitle=Synthesis,+crystal+structure+and+catalytic+activities+of+RuIII(bbpc(PPh3)Cl++H2bbpc=1,2-bis(4-tert-butylpyridine-2-+carboxamido)-4,5-dichlorobenzeneen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/DT9950002215en_HK
dc.identifier.scopuseid_2-s2.0-37049086579en_HK
dc.identifier.hkuros1481en_HK
dc.identifier.issue13en_HK
dc.identifier.spage2215en_HK
dc.identifier.epage2219en_HK
dc.identifier.isiWOS:A1995RJ20300015-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridKo, PH=14634145100en_HK
dc.identifier.scopusauthoridChen, TY=8060004000en_HK
dc.identifier.scopusauthoridZhu, J=7405688736en_HK
dc.identifier.scopusauthoridCheng, KF=7402997838en_HK
dc.identifier.scopusauthoridPeng, SM=35464852200en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.issnl1364-5447-

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