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Article: Equation of state and correlation function contact values of a hard sphere mixture

TitleEquation of state and correlation function contact values of a hard sphere mixture
Authors
Issue Date2000
PublisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.asp
Citation
Molecular Physics, 2000, v. 98 n. 15, p. 1005-1010 How to Cite?
AbstractRecently, there has been considerable activity in the study of the equation of state and correlation functions of a hard sphere mixture when the concentration of the large spheres is exceedingly small. This system is of considerable interest both as a simple prototype of an asymmetric mixture and as a simple but useful model of a colloidal suspension. We review our ad hoc formulae for the correlation function contact values and discuss the evidence, both pro and con, from exact and nearly exact theorems, computer simulations and experiment. Our conclusion is that our formulae are, on the whole, correct but the large sphere-large sphere correlation function contact value seems to need revision when the concentration of the large spheres is small but not exceedingly small. We propose a modest revision that preserves the seemingly correct aspects of our formula and this is in good agreement with the most recent simulations.
Persistent Identifierhttp://hdl.handle.net/10722/70347
ISSN
2015 Impact Factor: 1.837
2015 SCImago Journal Rankings: 0.781
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorHenderson, Den_HK
dc.contributor.authorChan, KYen_HK
dc.date.accessioned2010-09-06T06:22:01Z-
dc.date.available2010-09-06T06:22:01Z-
dc.date.issued2000en_HK
dc.identifier.citationMolecular Physics, 2000, v. 98 n. 15, p. 1005-1010en_HK
dc.identifier.issn0026-8976en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70347-
dc.description.abstractRecently, there has been considerable activity in the study of the equation of state and correlation functions of a hard sphere mixture when the concentration of the large spheres is exceedingly small. This system is of considerable interest both as a simple prototype of an asymmetric mixture and as a simple but useful model of a colloidal suspension. We review our ad hoc formulae for the correlation function contact values and discuss the evidence, both pro and con, from exact and nearly exact theorems, computer simulations and experiment. Our conclusion is that our formulae are, on the whole, correct but the large sphere-large sphere correlation function contact value seems to need revision when the concentration of the large spheres is small but not exceedingly small. We propose a modest revision that preserves the seemingly correct aspects of our formula and this is in good agreement with the most recent simulations.en_HK
dc.languageengen_HK
dc.publisherTaylor & Francis Ltd. The Journal's web site is located at http://www.tandf.co.uk/journals/titles/00268976.aspen_HK
dc.relation.ispartofMolecular Physicsen_HK
dc.titleEquation of state and correlation function contact values of a hard sphere mixtureen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0026-8976&volume=98&issue=15&spage=1005&epage=1010&date=2000&atitle=Equation+of+state+and+correlation+function+contact+values+of+a+hard+sphere+mixtureen_HK
dc.identifier.emailChan, KY:hrsccky@hku.hken_HK
dc.identifier.authorityChan, KY=rp00662en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1080/00268970050052051en_HK
dc.identifier.scopuseid_2-s2.0-0034632995en_HK
dc.identifier.hkuros58676en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0034632995&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume98en_HK
dc.identifier.issue15en_HK
dc.identifier.spage1005en_HK
dc.identifier.epage1010en_HK
dc.identifier.isiWOS:000088579000004-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridHenderson, D=7402988756en_HK
dc.identifier.scopusauthoridChan, KY=7406034142en_HK

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