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Article: Chemical reactivity of [Os3W(μ-H)(CO)14]− anion; synthesis and X-ray crystal structure of [Os3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}]

TitleChemical reactivity of [Os3W(μ-H)(CO)14]− anion; synthesis and X-ray crystal structure of [Os3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}]
Authors
Hui, JWSWong, WT
Issue Date1996
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/poly
Citation
Polyhedron, 1996, v. 15 n. 3, p. 541-543 How to Cite?
DOI: http://dx.doi.org/10.1016/0277-5387(95)00250-V
AbstractThe interaction of [Os3W(μ-H)(μ-CO)(CO)13]− anion with phenylacetylene in CHCl3 gave [Os3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}] is moderate yield. The compound has been fully characterized by both spectroscopic and crystallographic methods. Coupling of a phenylacetylene and a carbonyl ligand to form a cluster bound {μ3-η3-C(H)C(Ph)C(OH)} moiety is observed.
Persistent Identifierhttp://hdl.handle.net/10722/70336
ISSN
0277-5387
2023 Impact Factor: 2.4
2023 SCImago Journal Rankings: 0.379

 

DC FieldValueLanguage
dc.contributor.authorHui, JWSen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:21:55Z-
dc.date.available2010-09-06T06:21:55Z-
dc.date.issued1996en_HK
dc.identifier.citationPolyhedron, 1996, v. 15 n. 3, p. 541-543en_HK
dc.identifier.issn0277-5387en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70336-
dc.description.abstractThe interaction of [Os3W(μ-H)(μ-CO)(CO)13]− anion with phenylacetylene in CHCl3 gave [Os3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}] is moderate yield. The compound has been fully characterized by both spectroscopic and crystallographic methods. Coupling of a phenylacetylene and a carbonyl ligand to form a cluster bound {μ3-η3-C(H)C(Ph)C(OH)} moiety is observed.-
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/polyen_HK
dc.relation.ispartofPolyhedronen_HK
dc.titleChemical reactivity of [Os3W(μ-H)(CO)14]− anion; synthesis and X-ray crystal structure of [Os3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0277-5387&volume=15&issue=3&spage=541&epage=543&date=1996&atitle=Chemical+reactivity+of+[Os3W(m-H)(CO)14]-+anion;+synthesis+and+x-ray+crystal+structure+of+[Os3W(m-H)(CO)12{m=h3-C(Ph)C(OH)}]en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0277-5387(95)00250-V-
dc.identifier.scopuseid_2-s2.0-0039416066-
dc.identifier.hkuros21856en_HK
dc.identifier.hkuros14635-
dc.identifier.volume15-
dc.identifier.issue3-
dc.identifier.spage541-
dc.identifier.epage543-
dc.publisher.placeNetherlands-
dc.identifier.issnl0277-5387-

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