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Article: Metalloporphyrin-based oxidation systems: From biomimetic reactions to application in organic synthesis

TitleMetalloporphyrin-based oxidation systems: From biomimetic reactions to application in organic synthesis
Authors
Issue Date2009
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 2009 n. 27, p. 3996-4015 How to Cite?
AbstractThe oxidation of organic substrates catalyzed by metalloporphyrins constitutes a major class of biomimetic oxidation reactions used in modern synthetic chemistry. Ruthenium porphyrins are among the most extensively studied metalloporphyrin oxidation catalysts. This article provides a brief outline of the metalloporphyrin-based oxidation systems and is focused on the oxidation reactions catalyzed by ruthenium porphyrins performed in the author's laboratory. A series of ruthenium porphyrin catalysts, including those immobilized onto insoluble supports and covalently attached to soluble supports, promote the oxidation of a wide variety of organic substrates such as styrenes, cycloalkenes, α,β-unsaturated ketones, steroids, benzylic hydrocarbons and arenes with 2,6-dichloropyridine-N-oxide or air in up to >99% yields, with high regio-, chemo- and/or stereoselectivity, and with product turnovers of up to 3.0 × 104, demonstrating the potential application of ruthenium porphyrin-based oxidation systems in organic syntheses. © 2009 The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/70333
ISSN
2015 Impact Factor: 6.567
2015 SCImago Journal Rankings: 2.771
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_HK
dc.contributor.authorHuang, JSen_HK
dc.date.accessioned2010-09-06T06:21:53Z-
dc.date.available2010-09-06T06:21:53Z-
dc.date.issued2009en_HK
dc.identifier.citationChemical Communications, 2009 n. 27, p. 3996-4015en_HK
dc.identifier.issn1359-7345en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70333-
dc.description.abstractThe oxidation of organic substrates catalyzed by metalloporphyrins constitutes a major class of biomimetic oxidation reactions used in modern synthetic chemistry. Ruthenium porphyrins are among the most extensively studied metalloporphyrin oxidation catalysts. This article provides a brief outline of the metalloporphyrin-based oxidation systems and is focused on the oxidation reactions catalyzed by ruthenium porphyrins performed in the author's laboratory. A series of ruthenium porphyrin catalysts, including those immobilized onto insoluble supports and covalently attached to soluble supports, promote the oxidation of a wide variety of organic substrates such as styrenes, cycloalkenes, α,β-unsaturated ketones, steroids, benzylic hydrocarbons and arenes with 2,6-dichloropyridine-N-oxide or air in up to >99% yields, with high regio-, chemo- and/or stereoselectivity, and with product turnovers of up to 3.0 × 104, demonstrating the potential application of ruthenium porphyrin-based oxidation systems in organic syntheses. © 2009 The Royal Society of Chemistry.en_HK
dc.languageengen_HK
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_HK
dc.relation.ispartofChemical Communicationsen_HK
dc.titleMetalloporphyrin-based oxidation systems: From biomimetic reactions to application in organic synthesisen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1359-7345&volume=&spage=3996&epage=4015&date=2009&atitle=Metalloporphyrin-based+oxidation+systems:+from+biomimetic+reaction+to+application+in+organic+synthesisen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.emailHuang, JS:jshuang@hkucc.hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b901221den_HK
dc.identifier.pmid19568617-
dc.identifier.scopuseid_2-s2.0-67649841032en_HK
dc.identifier.hkuros159023en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-67649841032&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue27en_HK
dc.identifier.spage3996en_HK
dc.identifier.epage4015en_HK
dc.identifier.isiWOS:000267571100002-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK

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