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Article: Are adenine strands helical H-aggregates?

TitleAre adenine strands helical H-aggregates?
Authors
Issue Date2007
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journal/jpcbfk
Citation
Journal Of Physical Chemistry B, 2007, v. 111 n. 40, p. 11812-11816 How to Cite?
AbstractOn the basis of our quantum mechanical calculation, we propose that homogeneous single-stranded adenine bases (Ade-DNA) form helical H aggregates, and the photoexcited states can be described as Frenkel excitons. The calculated excitonic coupling between adjacent transition dipoles is in good agreement with the measured absorption spectrum of 20-base homogeneous adenine stacks that exhibits a blue shift of 2.6 nm relative to that of the monomeric species. © 2007 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/70322
ISSN
2015 Impact Factor: 3.187
2015 SCImago Journal Rankings: 1.414
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorHu, Len_HK
dc.contributor.authorZhao, Yen_HK
dc.contributor.authorWang, Fen_HK
dc.contributor.authorChen, Gen_HK
dc.contributor.authorMa, Cen_HK
dc.contributor.authorKwok, WMen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2010-09-06T06:21:47Z-
dc.date.available2010-09-06T06:21:47Z-
dc.date.issued2007en_HK
dc.identifier.citationJournal Of Physical Chemistry B, 2007, v. 111 n. 40, p. 11812-11816en_HK
dc.identifier.issn1520-6106en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70322-
dc.description.abstractOn the basis of our quantum mechanical calculation, we propose that homogeneous single-stranded adenine bases (Ade-DNA) form helical H aggregates, and the photoexcited states can be described as Frenkel excitons. The calculated excitonic coupling between adjacent transition dipoles is in good agreement with the measured absorption spectrum of 20-base homogeneous adenine stacks that exhibits a blue shift of 2.6 nm relative to that of the monomeric species. © 2007 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journal/jpcbfken_HK
dc.relation.ispartofJournal of Physical Chemistry Ben_HK
dc.subject.meshNucleic Acid Conformationen_HK
dc.subject.meshPoly A - chemistryen_HK
dc.subject.meshSpectrophotometryen_HK
dc.titleAre adenine strands helical H-aggregates?en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1520-6106&volume=111&spage=11812&epage=11816&date=2007&atitle=Are+Adenine+Strands+Helical+H-Aggregates?en_HK
dc.identifier.emailChen, G:ghc@yangtze.hku.hken_HK
dc.identifier.emailMa, C:macs@hkucc.hku.hken_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityChen, G=rp00671en_HK
dc.identifier.authorityMa, C=rp00758en_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jp070403men_HK
dc.identifier.pmid17880195-
dc.identifier.scopuseid_2-s2.0-35548999806en_HK
dc.identifier.hkuros143579en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-35548999806&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume111en_HK
dc.identifier.issue40en_HK
dc.identifier.spage11812en_HK
dc.identifier.epage11816en_HK
dc.identifier.eissn1520-5207-
dc.identifier.isiWOS:000249986900031-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridHu, L=7401557295en_HK
dc.identifier.scopusauthoridZhao, Y=8579132600en_HK
dc.identifier.scopusauthoridWang, F=35278563400en_HK
dc.identifier.scopusauthoridChen, G=35253368600en_HK
dc.identifier.scopusauthoridMa, C=7402924979en_HK
dc.identifier.scopusauthoridKwok, WM=7103129332en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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