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Article: Design, synthesis, photophysics, and ion-binding studies of a ditopic receptor based on goid(i) phosphine thiolate complex functionalized with crown ether and urea binding units

TitleDesign, synthesis, photophysics, and ion-binding studies of a ditopic receptor based on goid(i) phosphine thiolate complex functionalized with crown ether and urea binding units
Authors
Issue Date2010
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2010, v. 49 n. 5, p. 2273-2279 How to Cite?
AbstractA ditopic receptor based on gold(l) phosphine thiolate complex [(B15C5Ph2P)Au(SC6H4NHCONHC6H 5)] (1) together with a related crown-free analogue, [(Ph 3P)Au(SC6H4NHCONHC6H5)] (2), have been designed and synthesized and their photophysical properties studied. Complex 1 featured both a benzo-15-crown-5 cation-binding unit in the auxiliary phosphine ligand and a urea-functionalized thiolate as an anion receptor moiety. The anion- and cation-binding study, salt extraction ability, as well as the cooperativity have been studied using 1H NMR and ESI-MS techniques. © 2010 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/70307
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
Funding AgencyGrant Number
University of Hong Kong
URC Strategic Research Theme on Molecular Materials
Research Grants Council of Hong Kong Special Administrative Region, P. R. ChinaHKU 7050/08P
Funding Information:

V.W.-W.Y. acknowledges the support from The University of Hong Kong under the Distinguished Research Achievement Award Scheme and the URC Strategic Research Theme on Molecular Materials. This work has been supported by a General Research Fund (GRF) grant from the Research Grants Council of Hong Kong Special Administrative Region, P. R. China (HKU 7050/08P). X.H. acknowledges the receipt of a postgraduate studentship, administered by The University of Hong Kong.

References

 

DC FieldValueLanguage
dc.contributor.authorHe, Xen_HK
dc.contributor.authorYam, VWWen_HK
dc.date.accessioned2010-09-06T06:21:38Z-
dc.date.available2010-09-06T06:21:38Z-
dc.date.issued2010en_HK
dc.identifier.citationInorganic Chemistry, 2010, v. 49 n. 5, p. 2273-2279en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70307-
dc.description.abstractA ditopic receptor based on gold(l) phosphine thiolate complex [(B15C5Ph2P)Au(SC6H4NHCONHC6H 5)] (1) together with a related crown-free analogue, [(Ph 3P)Au(SC6H4NHCONHC6H5)] (2), have been designed and synthesized and their photophysical properties studied. Complex 1 featured both a benzo-15-crown-5 cation-binding unit in the auxiliary phosphine ligand and a urea-functionalized thiolate as an anion receptor moiety. The anion- and cation-binding study, salt extraction ability, as well as the cooperativity have been studied using 1H NMR and ESI-MS techniques. © 2010 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.titleDesign, synthesis, photophysics, and ion-binding studies of a ditopic receptor based on goid(i) phosphine thiolate complex functionalized with crown ether and urea binding unitsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0020-1669&volume=49&issue=5&spage=2273&epage=2279&date=2010&atitle=Design,+synthesis,+photophysics,+and+ion-binding+studies+of+a+ditopic+receptor+based+on+gold(I)+phosphine+thiolate+complex+functionalized+with+crown+ether+and+urea+binding+unitsen_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic9021068en_HK
dc.identifier.pmid20099846-
dc.identifier.scopuseid_2-s2.0-77649109589en_HK
dc.identifier.hkuros168995en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-77649109589&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume49en_HK
dc.identifier.issue5en_HK
dc.identifier.spage2273en_HK
dc.identifier.epage2279en_HK
dc.identifier.isiWOS:000274626200033-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridHe, X=7404409089en_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK

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