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Article: A highly luminescent tetranuclear copper(I) cluster: Structure and photophysical properties

TitleA highly luminescent tetranuclear copper(I) cluster: Structure and photophysical properties
Authors
KeywordsLuminesence
Metallomacrocycle
Tetranuclear Cu(I) cluster
Zigzag chain
Issue Date1998
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal Of Organometallic Chemistry, 1998, v. 556 n. 1-2, p. 169-172 How to Cite?
AbstractA tetranuclear copper(I) cluster Cu 4(CCPh) 4L 2 (1) [L=Ph 2PCH 2(CH 2OCH 2) 2CH 2PPh 2] prepared by self assembly reaction of [Cu(CCPh)] n with the bridging diphosphine ligand L comprises a Cu 2(L) 2 metallomacrocycle with two phenylethynyl copper(I) units encapsulated in the host site. The four Cu(I) are coplanar and arranged as a zigzag chain and the complex displays an intense emission at 522 nm with a lifetime of 9.8 μs and a quantum yield of 0.42 in dichloromethane.
Persistent Identifierhttp://hdl.handle.net/10722/70280
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorChan, WHen_HK
dc.contributor.authorZhang, ZZen_HK
dc.contributor.authorMak, TCWen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-09-06T06:21:24Z-
dc.date.available2010-09-06T06:21:24Z-
dc.date.issued1998en_HK
dc.identifier.citationJournal Of Organometallic Chemistry, 1998, v. 556 n. 1-2, p. 169-172en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/70280-
dc.description.abstractA tetranuclear copper(I) cluster Cu 4(CCPh) 4L 2 (1) [L=Ph 2PCH 2(CH 2OCH 2) 2CH 2PPh 2] prepared by self assembly reaction of [Cu(CCPh)] n with the bridging diphosphine ligand L comprises a Cu 2(L) 2 metallomacrocycle with two phenylethynyl copper(I) units encapsulated in the host site. The four Cu(I) are coplanar and arranged as a zigzag chain and the complex displays an intense emission at 522 nm with a lifetime of 9.8 μs and a quantum yield of 0.42 in dichloromethane.en_HK
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectLuminesenceen_HK
dc.subjectMetallomacrocycleen_HK
dc.subjectTetranuclear Cu(I) clusteren_HK
dc.subjectZigzag chainen_HK
dc.titleA highly luminescent tetranuclear copper(I) cluster: Structure and photophysical propertiesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=556&spage=169&epage=172&date=1998&atitle=A+highly+luminescent+tetranuclear+copper(I)+cluster:+structure+and+photophysical+propertiesen_HK
dc.identifier.emailChan, WH:waichan@hku.hken_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChan, WH=rp00667en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0022-328X(97)00702-X-
dc.identifier.scopuseid_2-s2.0-0001472105en_HK
dc.identifier.hkuros40276en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0001472105&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume556en_HK
dc.identifier.issue1-2en_HK
dc.identifier.spage169en_HK
dc.identifier.epage172en_HK
dc.identifier.isiWOS:000074106400020-
dc.publisher.placeSwitzerlanden_HK
dc.identifier.scopusauthoridChan, WH=13310083000en_HK
dc.identifier.scopusauthoridZhang, ZZ=13405280100en_HK
dc.identifier.scopusauthoridMak, TCW=7401931058en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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