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Article: Luminescence Behavior of Polynuclear Alkynylcopper(I) Phosphines

TitleLuminescence Behavior of Polynuclear Alkynylcopper(I) Phosphines
Authors
KeywordsAcetylide
Copper(I)
Luminescence
Tetranuclear
Trinuclear
Issue Date1999
PublisherSpringer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1040-7278
Citation
Journal Of Cluster Science, 1999, v. 10 n. 1, p. 37-69 How to Cite?
AbstractA series of soluble trinuclear and tetranuclear copper(I) complexes containing μ 3-η 1 acetylides [Cu 3(μ-dppm) 3(μ 3η 1-C ≡ CR)] 2+, [Cu 3(μ-dppm) 3(μ 3-η 1-C ≡ CR) 2] +, and [Cu 4(PPh 3) 4(μ 3-η 1-C ≡ CR) 4] have been synthesized and shown to exhibit rich photoluminescent behavior at room temperature. The electrochemistry of the trinuclear Cu(I) acetylide complexes and the excited-state redox properties of [Cu 3(μ-dppm) 3(μ 3η 1-C ≡ CC 6H 4OMe-p) 2] + have been investigated. The X-ray crystal structures of [Cu 3(μ-dppm) 3(μ 3-η 1-C ≡ CC 6H 4OMe-p) 2] + and [Cu 4(PPh 3) 4(μ 3η 1-C ≡ CC 6H 4OMe-p) 4] have been determined.
Persistent Identifierhttp://hdl.handle.net/10722/70259
ISSN
2015 Impact Factor: 1.664
2015 SCImago Journal Rankings: 0.416
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_HK
dc.contributor.authorFung, WKMen_HK
dc.contributor.authorCheung, KKen_HK
dc.date.accessioned2010-09-06T06:21:12Z-
dc.date.available2010-09-06T06:21:12Z-
dc.date.issued1999en_HK
dc.identifier.citationJournal Of Cluster Science, 1999, v. 10 n. 1, p. 37-69en_HK
dc.identifier.issn1040-7278en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70259-
dc.description.abstractA series of soluble trinuclear and tetranuclear copper(I) complexes containing μ 3-η 1 acetylides [Cu 3(μ-dppm) 3(μ 3η 1-C ≡ CR)] 2+, [Cu 3(μ-dppm) 3(μ 3-η 1-C ≡ CR) 2] +, and [Cu 4(PPh 3) 4(μ 3-η 1-C ≡ CR) 4] have been synthesized and shown to exhibit rich photoluminescent behavior at room temperature. The electrochemistry of the trinuclear Cu(I) acetylide complexes and the excited-state redox properties of [Cu 3(μ-dppm) 3(μ 3η 1-C ≡ CC 6H 4OMe-p) 2] + have been investigated. The X-ray crystal structures of [Cu 3(μ-dppm) 3(μ 3-η 1-C ≡ CC 6H 4OMe-p) 2] + and [Cu 4(PPh 3) 4(μ 3η 1-C ≡ CC 6H 4OMe-p) 4] have been determined.en_HK
dc.languageengen_HK
dc.publisherSpringer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1040-7278en_HK
dc.relation.ispartofJournal of Cluster Scienceen_HK
dc.subjectAcetylideen_HK
dc.subjectCopper(I)en_HK
dc.subjectLuminescenceen_HK
dc.subjectTetranuclearen_HK
dc.subjectTrinuclearen_HK
dc.titleLuminescence Behavior of Polynuclear Alkynylcopper(I) Phosphinesen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1040-7278&volume=10&issue=1&spage=37&epage=69&date=1999&atitle=Luminescence+behavior+of+polynuclear+alkynylcopper(I)+phosphinesen_HK
dc.identifier.emailYam, VWW:wwyam@hku.hken_HK
dc.identifier.authorityYam, VWW=rp00822en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1023/A:1022600600818-
dc.identifier.scopuseid_2-s2.0-0001936980en_HK
dc.identifier.hkuros43426en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0001936980&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume10en_HK
dc.identifier.issue1en_HK
dc.identifier.spage37en_HK
dc.identifier.epage69en_HK
dc.identifier.isiWOS:000078739300003-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridYam, VWW=18539304700en_HK
dc.identifier.scopusauthoridFung, WKM=37062711800en_HK
dc.identifier.scopusauthoridCheung, KK=7402406613en_HK

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