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Article: Syntheses and molecular structures of heterometallic carbonyl clusters derived from the triruthenium carbonyl methoxynitrido cluster; crystal and molecular structures of [Ru2Mo(μ-H)(CO)8(η5-C5H5)(μ3-NOMe)], [Ru2Mo(μ-H)(CO)8(η5-C5H5)(μ3-NH)] and [Ru3(CO)10(μ-NH2)(μ3-Hg){Mo(η5-C5H5)(CO)3}]

TitleSyntheses and molecular structures of heterometallic carbonyl clusters derived from the triruthenium carbonyl methoxynitrido cluster; crystal and molecular structures of [Ru2Mo(μ-H)(CO)8(η5-C5H5)(μ3-NOMe)], [Ru2Mo(μ-H)(CO)8(η5-C5H5)(μ3-NH)] and [Ru3(CO)10(μ-NH2)(μ3-Hg){Mo(η5-C5H5)(CO)3}]
Authors
KeywordsRuthenium
Molybdenum
Cluster
Methoxynitrido
Nitrene
Issue Date1999
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 1999, v. 577 n. 2, p. 323-329 How to Cite?
AbstractReaction of [Ru3(CO)9(μ3-CO)(μ3-NOMe)] 1 with stoichiometric amounts of the hydrido complex [(η5-C5H5)Mo(CO)3H] in THF at room temperature (r.t.) for 3 days affords the isolation of two new heterometallic trinuclear clusters namely [Ru2Mo(μ-H)(CO)8(η5-C5H5)(μ3-NOMe)] 2 and [Ru2Mo(μ-H)(CO)8(η5-C5H5)(μ3-NH)] 3 which both consist of a triangular Ru2Mo core capped by a NR fragment (2: R=OMe; 3: R=H). However, the reaction of 1 with the organomercurial derivative [{(η5-C5H5)Mo(CO)3}2Hg] resulted in the formation of a pentanuclear complex [Ru3(CO)10(μ-NH2)(μ3-Hg){Mo(η5-C5H5)(CO)3}] 4 in which a (η5-C5H5)Mo(CO)3Hg fragment bridges the Ru3 core on the opposite side of the amido group.
Persistent Identifierhttp://hdl.handle.net/10722/70236
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLee, KKHen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:20:59Z-
dc.date.available2010-09-06T06:20:59Z-
dc.date.issued1999en_HK
dc.identifier.citationJournal of Organometallic Chemistry, 1999, v. 577 n. 2, p. 323-329en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/70236-
dc.description.abstractReaction of [Ru3(CO)9(μ3-CO)(μ3-NOMe)] 1 with stoichiometric amounts of the hydrido complex [(η5-C5H5)Mo(CO)3H] in THF at room temperature (r.t.) for 3 days affords the isolation of two new heterometallic trinuclear clusters namely [Ru2Mo(μ-H)(CO)8(η5-C5H5)(μ3-NOMe)] 2 and [Ru2Mo(μ-H)(CO)8(η5-C5H5)(μ3-NH)] 3 which both consist of a triangular Ru2Mo core capped by a NR fragment (2: R=OMe; 3: R=H). However, the reaction of 1 with the organomercurial derivative [{(η5-C5H5)Mo(CO)3}2Hg] resulted in the formation of a pentanuclear complex [Ru3(CO)10(μ-NH2)(μ3-Hg){Mo(η5-C5H5)(CO)3}] 4 in which a (η5-C5H5)Mo(CO)3Hg fragment bridges the Ru3 core on the opposite side of the amido group.-
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectRuthenium-
dc.subjectMolybdenum-
dc.subjectCluster-
dc.subjectMethoxynitrido-
dc.subjectNitrene-
dc.titleSyntheses and molecular structures of heterometallic carbonyl clusters derived from the triruthenium carbonyl methoxynitrido cluster; crystal and molecular structures of [Ru2Mo(μ-H)(CO)8(η5-C5H5)(μ3-NOMe)], [Ru2Mo(μ-H)(CO)8(η5-C5H5)(μ3-NH)] and [Ru3(CO)10(μ-NH2)(μ3-Hg){Mo(η5-C5H5)(CO)3}]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=577&spage=323&epage=329&date=1999&atitle=Syntheses+and+molecular+structures+of+heterometallic+carbonyl+clusters+derived+from+the+triruthenium+carbonyl+methoxynitrido+cluster;+crystal+and+molecular+structures+of+[Ru2Mo(m-H)(CO)8(h5-C5H5)(m3-NOMe)],+[Ru2Mo(m-H)(en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/S0022-328X(98)01092-4-
dc.identifier.hkuros45575en_HK
dc.identifier.issue2-
dc.identifier.isiWOS:000079632800023-

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