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Article: Syntheses and molecular structures of mononuclear ruthenium carbonyl complexes containing 2,1-naphthoquinone-2-oximato ligands

TitleSyntheses and molecular structures of mononuclear ruthenium carbonyl complexes containing 2,1-naphthoquinone-2-oximato ligands
Authors
Issue Date1997
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal Of Organometallic Chemistry, 1997, v. 547 n. 2, p. 329-335 How to Cite?
AbstractThe reaction between [Ru3(CO)12] and 2,1-naphthoquinone-2-oxime or known as 2-nitroso-1-naphthol afforded two isomeric mononuclear ruthenium carbonyl complexes trans-[Ru(η2-OC10H6NO)2(CO)2] 1 and cis-[Ru(η2-OC10H6NO)2(CO)2] 2, in which the two bidentate 2-naphthoquinone-1-oximato ligands chelated on the ruthenium centre in different spacial orientation via the coordination of naphtholic oxygen and oxime nitrogen atoms. Both 1 and 2 adopt a cis-dicarbonyl configuration and the carbonyl groups can be replaced by the N-donor ligands in the presence of trimethylamine-N-oxide via the reaction intermediates, trans-[Ru(η2-OC10H6NO)2(CO)(NMe3)] 4 and cis-[Ru(η2-OC10H6NO)2(CO)(NMe3)] 3a respectively. Complexes 1, 3a and 4 have been fully characterised by spectroscopic methods and their molecular structures were established by X-ray crystallographic analyses. © 1997 Elsevier Science S.A.
Persistent Identifierhttp://hdl.handle.net/10722/70232
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLee, KKHen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:20:57Z-
dc.date.available2010-09-06T06:20:57Z-
dc.date.issued1997en_HK
dc.identifier.citationJournal Of Organometallic Chemistry, 1997, v. 547 n. 2, p. 329-335en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/70232-
dc.description.abstractThe reaction between [Ru3(CO)12] and 2,1-naphthoquinone-2-oxime or known as 2-nitroso-1-naphthol afforded two isomeric mononuclear ruthenium carbonyl complexes trans-[Ru(η2-OC10H6NO)2(CO)2] 1 and cis-[Ru(η2-OC10H6NO)2(CO)2] 2, in which the two bidentate 2-naphthoquinone-1-oximato ligands chelated on the ruthenium centre in different spacial orientation via the coordination of naphtholic oxygen and oxime nitrogen atoms. Both 1 and 2 adopt a cis-dicarbonyl configuration and the carbonyl groups can be replaced by the N-donor ligands in the presence of trimethylamine-N-oxide via the reaction intermediates, trans-[Ru(η2-OC10H6NO)2(CO)(NMe3)] 4 and cis-[Ru(η2-OC10H6NO)2(CO)(NMe3)] 3a respectively. Complexes 1, 3a and 4 have been fully characterised by spectroscopic methods and their molecular structures were established by X-ray crystallographic analyses. © 1997 Elsevier Science S.A.en_HK
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.titleSyntheses and molecular structures of mononuclear ruthenium carbonyl complexes containing 2,1-naphthoquinone-2-oximato ligandsen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=547&spage=329&epage=335&date=1997&atitle=Syntheses+and+molecular+structures+of+mononuclear+ruthenium+carbonyl+complexes+containing+2,1-naphthoquinone-2-oximato+ligandsen_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0022-328X(97)00392-6-
dc.identifier.scopuseid_2-s2.0-0031521521en_HK
dc.identifier.hkuros31384en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0031521521&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume547en_HK
dc.identifier.issue2en_HK
dc.identifier.spage329en_HK
dc.identifier.epage335en_HK
dc.identifier.isiWOS:000071450800014-
dc.publisher.placeSwitzerlanden_HK
dc.identifier.scopusauthoridLee, KKH=7501503428en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK

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