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Article: Synthesis and crystal structure of [(η5:η5-C5H4PPh2)Tl]∞ and the divalent ytterbium derivative [(η5-C5H4PPh2)2Yb(DME)]

TitleSynthesis and crystal structure of [(η5:η5-C5H4PPh2)Tl]∞ and the divalent ytterbium derivative [(η5-C5H4PPh2)2Yb(DME)]
Authors
KeywordsThallium
Ytterbium
Cyclopentadienyl
Crystal structure
Issue Date1995
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 1995, v. 495 n. 1-2, p. 203-208 How to Cite?
AbstractThe complex [(diphenylphosphino)cyclopentadienyl]thallium [(η5:η5-C5H4PPh2)Tl]∞ (1) and the divalent ytterbium compound [(η5-C5H4PPh2)2Yb(DME)] (2) (DME = dimethoxyethane) made from it have been synthesized and characterized by IR, 1H NMR and 31P NMR spectroscopy and X-ray diffraction studies. In the crystal 1, polymeric zigzag chains of alternating thallium ions and cyclopentadienyl rings, form, with the neighboring chains were connected by the weak interactions between phosphorus and thallium atoms. In contrast, 2 is a neutral monomer with two dangling phosphorus atoms.
Persistent Identifierhttp://hdl.handle.net/10722/70230
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLin, Gen_HK
dc.contributor.authorWong, WTen_HK
dc.date.accessioned2010-09-06T06:20:56Z-
dc.date.available2010-09-06T06:20:56Z-
dc.date.issued1995en_HK
dc.identifier.citationJournal of Organometallic Chemistry, 1995, v. 495 n. 1-2, p. 203-208en_HK
dc.identifier.issn0022-328Xen_HK
dc.identifier.urihttp://hdl.handle.net/10722/70230-
dc.description.abstractThe complex [(diphenylphosphino)cyclopentadienyl]thallium [(η5:η5-C5H4PPh2)Tl]∞ (1) and the divalent ytterbium compound [(η5-C5H4PPh2)2Yb(DME)] (2) (DME = dimethoxyethane) made from it have been synthesized and characterized by IR, 1H NMR and 31P NMR spectroscopy and X-ray diffraction studies. In the crystal 1, polymeric zigzag chains of alternating thallium ions and cyclopentadienyl rings, form, with the neighboring chains were connected by the weak interactions between phosphorus and thallium atoms. In contrast, 2 is a neutral monomer with two dangling phosphorus atoms.-
dc.languageengen_HK
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchemen_HK
dc.relation.ispartofJournal of Organometallic Chemistryen_HK
dc.subjectThallium-
dc.subjectYtterbium-
dc.subjectCyclopentadienyl-
dc.subjectCrystal structure-
dc.titleSynthesis and crystal structure of [(η5:η5-C5H4PPh2)Tl]∞ and the divalent ytterbium derivative [(η5-C5H4PPh2)2Yb(DME)]en_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0022-328X&volume=495 Nos1-2&spage=203&epage=208&date=1995&atitle=Synthesis+and+X-ray+crystal+structures+of+[(h5:h5-C5H4PPh2)Tl]++and+its+divalent+ytterbium+derivative+of+[(h5-C5H4PPh2)2Yb(DME)]en_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.identifier.doi10.1016/0022-328X(95)05463-Y-
dc.identifier.hkuros14575en_HK
dc.identifier.volume495-
dc.identifier.issue1-2-
dc.identifier.spage203-
dc.identifier.epage208-
dc.identifier.isiWOS:A1995RD76900022-
dc.publisher.placeSwitzerland-

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