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Article: Solvation effects and short-time photodissociation dynamics of CH2I2 in solution from resonance Raman spectroscopy

TitleSolvation effects and short-time photodissociation dynamics of CH2I2 in solution from resonance Raman spectroscopy
Authors
Issue Date1995
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cplett
Citation
Chemical Physics Letters, 1995, v. 235 n. 3-4, p. 260-267 How to Cite?
AbstractResonance Raman spectra of CH2I2 in cyclohexane solution have been obtained within the directly dissociative A-state absorption band of CH2I2 at excitation wavelengths of 355 and 341.5 nm. We find several intense vibrational bands in the solution phase spectra that are not observed in a previously reported 355 nm gas phase spectrum indicating that solvation effects are important in the Franck-Condon region of the first electronic excited state of CH2I2. The solution phase short-time photodissociation dynamics appears to have more motion in the ICI bending coordinate than the gas phase photodissociation. © 1995.
Persistent Identifierhttp://hdl.handle.net/10722/70221
ISSN
2015 Impact Factor: 1.86
2015 SCImago Journal Rankings: 0.757

 

DC FieldValueLanguage
dc.contributor.authorMing Kwok, Wen_HK
dc.contributor.authorLee Phillips, Den_HK
dc.date.accessioned2010-09-06T06:20:51Z-
dc.date.available2010-09-06T06:20:51Z-
dc.date.issued1995en_HK
dc.identifier.citationChemical Physics Letters, 1995, v. 235 n. 3-4, p. 260-267en_HK
dc.identifier.issn0009-2614en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70221-
dc.description.abstractResonance Raman spectra of CH2I2 in cyclohexane solution have been obtained within the directly dissociative A-state absorption band of CH2I2 at excitation wavelengths of 355 and 341.5 nm. We find several intense vibrational bands in the solution phase spectra that are not observed in a previously reported 355 nm gas phase spectrum indicating that solvation effects are important in the Franck-Condon region of the first electronic excited state of CH2I2. The solution phase short-time photodissociation dynamics appears to have more motion in the ICI bending coordinate than the gas phase photodissociation. © 1995.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/cpletten_HK
dc.relation.ispartofChemical Physics Lettersen_HK
dc.rightsChemical Physics Letters. Copyright © Elsevier BV.en_HK
dc.titleSolvation effects and short-time photodissociation dynamics of CH2I2 in solution from resonance Raman spectroscopyen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0009-2614&volume=235&spage=260&epage=267&date=1995&atitle=Solvation+effects+and+short+time+photodissociation+dynamics+of+CH2I2+in+solution+from+resonance+Raman+spectroscopyen_HK
dc.identifier.emailLee Phillips, D:phillips@hku.hken_HK
dc.identifier.authorityLee Phillips, D=rp00770en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0009-2614(95)00122-K-
dc.identifier.scopuseid_2-s2.0-58149323066en_HK
dc.identifier.hkuros8609en_HK
dc.identifier.hkuros518-
dc.identifier.volume235en_HK
dc.identifier.issue3-4en_HK
dc.identifier.spage260en_HK
dc.identifier.epage267en_HK
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridMing Kwok, W=8089592800en_HK
dc.identifier.scopusauthoridLee Phillips, D=7404519365en_HK

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