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Article: Synthesis, structure and catalytic properties of Re(I)-NOBIN Schiff base complex

TitleSynthesis, structure and catalytic properties of Re(I)-NOBIN Schiff base complex
Authors
KeywordsCatalytic property
Chiral
NOBIN Schiff base
Rhenium complex
Issue Date2005
PublisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inoche
Citation
Inorganic Chemistry Communications, 2005, v. 8 n. 3, p. 307-309 How to Cite?
AbstractThe chiral mononuclear complex of Re(I)-NOBIN Schiff base (NOBIN = 1-amino-1′-hydroxylbinaphthyl) was synthesized via the reaction of Re(CO)5Cl and corresponding tridentate ligand in methanol. The structure analysis reveals that the central metal coordinates with nitrogen atom of imine and oxygen atom of salicylaldehyde form a six-membered ring, while the left uncoordinated phenol group adjacent to the binaphthyl backbone forms a hydrogen bonding with water molecule coordinated with the Re(I) ion. This mononuclear complex shows some catalytic ability in asymmetric epoxidation and aziridination with moderate results. © 2004 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/70208
ISSN
2015 Impact Factor: 1.762
2015 SCImago Journal Rankings: 0.489
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLi, ZKen_HK
dc.contributor.authorLi, Yen_HK
dc.contributor.authorLei, Len_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorZhou, XGen_HK
dc.date.accessioned2010-09-06T06:20:44Z-
dc.date.available2010-09-06T06:20:44Z-
dc.date.issued2005en_HK
dc.identifier.citationInorganic Chemistry Communications, 2005, v. 8 n. 3, p. 307-309en_HK
dc.identifier.issn1387-7003en_HK
dc.identifier.urihttp://hdl.handle.net/10722/70208-
dc.description.abstractThe chiral mononuclear complex of Re(I)-NOBIN Schiff base (NOBIN = 1-amino-1′-hydroxylbinaphthyl) was synthesized via the reaction of Re(CO)5Cl and corresponding tridentate ligand in methanol. The structure analysis reveals that the central metal coordinates with nitrogen atom of imine and oxygen atom of salicylaldehyde form a six-membered ring, while the left uncoordinated phenol group adjacent to the binaphthyl backbone forms a hydrogen bonding with water molecule coordinated with the Re(I) ion. This mononuclear complex shows some catalytic ability in asymmetric epoxidation and aziridination with moderate results. © 2004 Elsevier B.V. All rights reserved.en_HK
dc.languageengen_HK
dc.publisherElsevier BV. The Journal's web site is located at http://www.elsevier.com/locate/inocheen_HK
dc.relation.ispartofInorganic Chemistry Communicationsen_HK
dc.rightsInorganic Chemistry Communications. Copyright © Elsevier BV.en_HK
dc.subjectCatalytic propertyen_HK
dc.subjectChiralen_HK
dc.subjectNOBIN Schiff baseen_HK
dc.subjectRhenium complexen_HK
dc.titleSynthesis, structure and catalytic properties of Re(I)-NOBIN Schiff base complexen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1387-7003&volume=8&spage=307&epage=309&date=2005&atitle=Synthesis,+structure+and+catalytic+properties+of+Re(I)-NOBIN+Schiff+base+complexen_HK
dc.identifier.emailChe, CM:cmche@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.inoche.2004.12.020en_HK
dc.identifier.scopuseid_2-s2.0-13544260595en_HK
dc.identifier.hkuros105848en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-13544260595&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume8en_HK
dc.identifier.issue3en_HK
dc.identifier.spage307en_HK
dc.identifier.epage309en_HK
dc.identifier.isiWOS:000227223400020-
dc.publisher.placeNetherlandsen_HK
dc.identifier.scopusauthoridLi, ZK=8659535500en_HK
dc.identifier.scopusauthoridLi, Y=36071673800en_HK
dc.identifier.scopusauthoridLei, L=36991306000en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridZhou, XG=7410094013en_HK

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